Personal information

Spain

Biography

Since 1983, she has been part of several research groups dedicated to organic synthesis and to the synthesis of biomolecule derivatives for NMR structural biology studies. Funding has been due to 9 public research projects (the latest RT2018-095588-B-100). In addition, she has collaborated with pharmaceutical companies such as Eli-Lilly (5-year contract) for the synthesis of new ligands for the metabotropic glutamic acid receptors, and CsFlowChem a company specialized in flow chemistry. My scientific production in the group of Prof. Pérez-Castells summarized up to now in 59 indexed publications, most of them published in high impact journals (of the first quartile, Q1), 42 communications to conferences and 5 Book chapters have also been published. The main line of the group is based on developing methodologies for the Pauson-Khand reaction, such as the introduction of aromatic enynes as substrates or the promotion by molecular sieves and the development of this reaction in a plug flow reactor; also, the applications of ruthenium carbenes in combined metathesis reactions with Diels-Alder and others, as well as non-metathetic processes such as cyclopropanations, cycloisomerizations and [2+2+2] cyclotrimerizations. The group has disclosed the synthesis of molecules with potential activity such as iminosugars and enzyme inhibitors (in collaboration with Prof. Javier Cañada from CSIC). What is more, the group has collaborated with Prof. Jiménez-Barbero (CIB) and with Prof. Thomas Peters (U. of Lübeck, Germany) synthesizing carbohydrate derivatives linked to lanthanides for the use of paramagnetic effects in structural studies by NMR. In the coming years, the main interests of the group will be the development of new reactions in flow reactors in collaboration with the company CsFlowChem, including their scaling up and applications in drug synthesis; the study of new reactivity catalyzed by ruthenium and cobalt complexes in unsaturated systems, especially cyclopropenes; and the synthesis of paramagnetic tags to solve structural biology problems.
General quality indicators for scientific production: She has been granted 5 six-year terms (sexenios, the actual one: 2010-2015), by an agreement with ANECA of USP-CEU. 91 articles listed in the WOS, which have received a total of 2647 citations with an average of 29.09 per article. Of the 91 publications, 55 articles belong to the first quartile (Q1). The h-index is currently 25. All this data has been obtained
from the Thomson Reuters Web of Science.
Contributions to formation of students and young researchers: Throughout 34 years of teaching experience she has taught Organic Chemistry (Chemistry and Pharmacy), Pharmaceutical Chemistry, and Pharmaceutical Chemistry; postgraduate PhD courses such as Natural Products and master courses such as Structural Elucidation of Drugs, and Natural Products as a Source of New
Drugs. He has supervised 9 doctoral theses, and 19 dissertations, DEAs or master's thesis, as well as numerous final degree projects.

Activities

Employment (1)

Universidad CEU San Pablo: Madrid, ES

Researcher (Academic) (Quimica y Bioquimica)
Employment
Source: Self-asserted source
GEMA DOMINGUEZ MARTIN

Education and qualifications (1)

Universidad Complutense de Madrid: Madrid, MADRID, ES

1983-01-01 to 1986-06-13 | Doctor (Química Orgánica)
Qualification
Source: Self-asserted source
GEMA DOMINGUEZ MARTIN

Works (50 of 89)

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Page 1 of 2

Effect of Lauric vs. Oleic Acid-Enriched Diets on Leptin Autoparacrine Signalling in Male Mice

Biomedicines
2022-08-02 | Journal article
Contributors: Jesús Fernández-Felipe; Adrián Plaza; Gema Domínguez; Javier Pérez-Castells; Victoria Cano; Francesco Cioni; Nuria Del Olmo; Mariano Ruiz-Gayo; Beatriz Merino
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Crossref
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Synthesis and evaluation of novel iminosugars prepared from natural amino acids

Molecules
2021 | Journal article
EID:

2-s2.0-85100125812

Part of ISSN: 14203049
Contributors: Puet, A.; Domínguez, G.; Cañada, F.J.; Pérez-Castells, J.
Source: Self-asserted source
GEMA DOMINGUEZ MARTIN via Scopus - Elsevier

Amino Acid-Based Synthesis and Glycosidase Inhibition of Cyclopropane-Containing Iminosugars

ACS Omega
2020 | Journal article
EID:

2-s2.0-85097737725

Part of ISSN: 24701343
Contributors: Puet, A.; Domínguez, G.; Cañada, F.J.; Pérez-Castells, J.
Source: Self-asserted source
GEMA DOMINGUEZ MARTIN via Scopus - Elsevier

Flow Chemistry for Cycloaddition Reactions

ChemSusChem
2020 | Journal article
EID:

2-s2.0-85089505941

Part of ISSN: 1864564X 18645631
Contributors: García-Lacuna, J.; Domínguez, G.; Pérez-Castells, J.
Source: Self-asserted source
GEMA DOMINGUEZ MARTIN via Scopus - Elsevier

Ruthenium Catalyzed Rearrangement of Ene-cyclopropenes. Divergent Reaction Pathways

Journal of Organic Chemistry
2019 | Journal article
EID:

2-s2.0-85060177113

Part of ISSN: 15206904 00223263
Contributors: López-Rodríguez, A.; Domínguez, G.; Pérez-Castells, J.
Source: Self-asserted source
GEMA DOMINGUEZ MARTIN via Scopus - Elsevier

Synthesis of treprostinil: Key claisen rearrangement and catalytic pauson-khand reactions in continuous flow

Organic and Biomolecular Chemistry
2019 | Journal article
EID:

2-s2.0-85074620092

Part of ISSN: 14770520
Contributors: García-Lacuna, J.; Domínguez, G.; Blanco-Urgoiti, J.; Pérez-Castells, J.
Source: Self-asserted source
GEMA DOMINGUEZ MARTIN via Scopus - Elsevier
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Avenues to Characterize the Interactions of Extended N-Glycans with Proteins by NMR Spectroscopy: The Influenza Hemagglutinin Case

Angewandte Chemie - International Edition
2018 | Journal article
EID:

2-s2.0-85055116222

Part of ISSN: 15213773 14337851
Contributors: Fernández de Toro, B.; Peng, W.; Thompson, A.J.; Domínguez, G.; Cañada, F.J.; Pérez-Castells, J.; Paulson, J.C.; Jiménez-Barbero, J.; Canales, Á.
Source: Self-asserted source
GEMA DOMINGUEZ MARTIN via Scopus - Elsevier

Cholecystokinin is involved in triglyceride fatty acid uptake by rat adipose tissue

Journal of Endocrinology
2018 | Journal article
EID:

2-s2.0-85042478306

Part of ISSN: 14796805 00220795
Contributors: Plaza, A.; Merino, B.; Cano, V.; Domínguez, G.; Pérez-Castells, J.; Fernández-Alfonso, M.S.; Sengenès, C.; Chowen, J.A.; Ruiz-Gayo, M.
Source: Self-asserted source
GEMA DOMINGUEZ MARTIN via Scopus - Elsevier

Cobalt Octacarbonyl-Catalyzed Scalable Alkyne Cyclotrimerization and Crossed [2 + 2 + 2]-Cycloaddition Reaction in a Plug Flow Reactor

Organic letters
2018 | Journal article
EID:

2-s2.0-85052994456

Part of ISSN: 15237052
Contributors: García-Lacuna, J.; Domínguez, G.; Blanco-Urgoiti, J.; Pérez-Castells, J.
Source: Self-asserted source
GEMA DOMINGUEZ MARTIN via Scopus - Elsevier

A catalytic scalable Pauson-Khand reaction in a plug flow reactor

Chemical Communications
2017 | Journal article
EID:

2-s2.0-85017128648

Part of ISSN: 1364548X 13597345
Contributors: García-Lacuna, J.; Domínguez, G.; Blanco-Urgoiti, J.; Pérez-Castells, J.
Source: Self-asserted source
GEMA DOMINGUEZ MARTIN via Scopus - Elsevier

Breaking the Limits in Analyzing Carbohydrate Recognition by NMR Spectroscopy: Resolving Branch-Selective Interaction of a Tetra-Antennary N-Glycan with Lectins

Angewandte Chemie - International Edition
2017 | Journal article
EID:

2-s2.0-85033782658

Part of ISSN: 15213773 14337851
Contributors: Canales, A.; Boos, I.; Perkams, L.; Karst, L.; Luber, T.; Karagiannis, T.; Domínguez, G.; Cañada, F.J.; Pérez-Castells, J.; Häussinger, D. et al.
Source: Self-asserted source
GEMA DOMINGUEZ MARTIN via Scopus - Elsevier

Microwave-Mediated Sulfonium Ylide Cyclopropanation. Stereoselective Synthesis of Cyclopropa[c]pentalenes

ChemistrySelect
2017 | Journal article
EID:

2-s2.0-85031016969

Part of ISSN: 23656549
Contributors: López-Rodríguez, A.; Domínguez, G.; Pérez-Castells, J.
Source: Self-asserted source
GEMA DOMINGUEZ MARTIN via Scopus - Elsevier

Synthesis of Novel Iminosugar Derivatives Based on a 2-Azabi-ccyclo[41.0]heptane Skeleton

Synthesis (Germany)
2017 | Journal article
EID:

2-s2.0-85029752328

Part of ISSN: 1437210X 00397881
Contributors: López-Rodríguez, A.; Domínguez, G.; Pérez-Castells, J.
Source: Self-asserted source
GEMA DOMINGUEZ MARTIN via Scopus - Elsevier

A rigid lanthanide binding tag to aid NMR studies of a 70 kDa homodimeric coat protein of human norovirus

Chemical Communications
2016 | Journal article
EID:

2-s2.0-84983142797

Part of ISSN: 1364548X 13597345
Contributors: Mallagaray, A.; Domínguez, G.; Peters, T.; Pérez-Castells, J.
Source: Self-asserted source
GEMA DOMINGUEZ MARTIN via Scopus - Elsevier

Alkenes in [2+2+2] Cycloadditions

Chemistry - A European Journal
2016 | Journal article
EID:

2-s2.0-84959418905

Part of ISSN: 15213765 09476539
Contributors: Domínguez, G.; Pérez-Castells, J.
Source: Self-asserted source
GEMA DOMINGUEZ MARTIN via Scopus - Elsevier

Ruthenium alkylidene-catalyzed reaction of 1,6-heptadiynes with alkenes

Journal of Organic Chemistry
2015 | Journal article
EID:

2-s2.0-84923368759

Part of ISSN: 15206904 00223263
Contributors: Alvarez, S.; Medina, S.; Domínguez, G.; Pérez-Castells, J.
Source: Self-asserted source
GEMA DOMINGUEZ MARTIN via Scopus - Elsevier

[2+2+2] Cycloadditions

Comprehensive Organic Synthesis: Second Edition
2014 | Book chapter
EID:

2-s2.0-84903493270

Contributors: Domínguez, G.; Pérez-Castells, J.
Source: Self-asserted source
GEMA DOMINGUEZ MARTIN via Scopus - Elsevier

Lanthanide-chelating carbohydrate conjugates are useful tools to characterize carbohydrate conformation in solution and sensitive sensors to detect carbohydrate-protein interactions

Journal of the American Chemical Society
2014 | Journal article
EID:

2-s2.0-84901922812

Part of ISSN: 15205126 00027863
Contributors: Canales, A.; Mallagaray, A.; Berbís, M.A.; Navarro-Vázquez, A.; Domínguez, G.; Cañada, F.J.; André, S.; Gabius, H.-J.; Pérez-Castells, J.; Jiménez-Barbero, J.
Source: Self-asserted source
GEMA DOMINGUEZ MARTIN via Scopus - Elsevier

Cyclotrimerization of alkynes and isocyanates/isothiocyanates catalyzed by ruthenium-alkylidene complexes

Journal of Organic Chemistry
2013 | Journal article
EID:

2-s2.0-84885147235

Part of ISSN: 00223263 15206904
Contributors: Alvarez, S.; Medina, S.; Domínguez, G.; Pérez-Castells, J.
Source: Self-asserted source
GEMA DOMINGUEZ MARTIN via Scopus - Elsevier

Unusual skeletal rearrangement of unsaturated seven-membered lactams into fused pyrrolidinolactones

European Journal of Organic Chemistry
2013 | Journal article
EID:

2-s2.0-84877750967

Part of ISSN: 1434193X 10990690
Contributors: Álvarez, S.; Domínguez, G.; Gradillas, A.; Pérez-Castells, J.
Source: Self-asserted source
GEMA DOMINGUEZ MARTIN via Scopus - Elsevier

Cycloisomerization of dienes and enynes catalysed by a modified ruthenium carbene species

Organic and Biomolecular Chemistry
2012 | Journal article
EID:

2-s2.0-84864630019

Part of ISSN: 14770520
Contributors: Mallagaray, Á.; Mohammadiannejad-Abbasabadi, K.; Medina, S.; Domínguez, G.; Pérez-Castells, J.
Source: Self-asserted source
GEMA DOMINGUEZ MARTIN via Scopus - Elsevier

Efficient generation of pyridines by ruthenium carbene mediated [2 + 2 + 2] cyclotrimerization

Organic Letters
2012 | Journal article
EID:

2-s2.0-84867341470

Part of ISSN: 15237060 15237052
Contributors: Medina, S.; Domínguez, G.; Pérez-Castells, J.
Source: Self-asserted source
GEMA DOMINGUEZ MARTIN via Scopus - Elsevier

Medium-sized and strained heterocycles from non-catalysed and gold-catalysed conversions of β-carbolines

Organic and Biomolecular Chemistry
2012 | Journal article
EID:

2-s2.0-84865202475

Part of ISSN: 14770520
Contributors: Medina, S.; González-Gómez, Á.; Domínguez, G.; Pérez-Castells, J.
Source: Self-asserted source
GEMA DOMINGUEZ MARTIN via Scopus - Elsevier

Synthesis and biological evaluation of novel indolocarbazoles with anti-angiogenic activity

European Journal of Medicinal Chemistry
2012 | Journal article
EID:

2-s2.0-84856001592

Part of ISSN: 02235234 17683254
Contributors: Acero, N.; Braña, M.F.; Añorbe, L.; Domínguez, G.; Muñoz-Mingarro, D.; Mitjans, F.; Piulats, J.
Source: Self-asserted source
GEMA DOMINGUEZ MARTIN via Scopus - Elsevier

A rigid lanthanide binding tag for NMR structural analysis of carbohydrates

Chemical Communications
2011 | Journal article
EID:

2-s2.0-79959795584

Part of ISSN: 1364548X 13597345
Contributors: Mallagaray, A.; Canales, A.; Domínguez, G.; Jiménez-Barbero, J.; Pérez-Castells, J.
Source: Self-asserted source
GEMA DOMINGUEZ MARTIN via Scopus - Elsevier

Chemistry of β-carbolines as synthetic intermediates

European Journal of Organic Chemistry
2011 | Journal article
EID:

2-s2.0-82955163906

Part of ISSN: 1434193X 10990690
Contributors: Domínguez, G.; Pérez-Castells, J.
Source: Self-asserted source
GEMA DOMINGUEZ MARTIN via Scopus - Elsevier

Erratum: Recent advances in [2+2+2] cycloaddition reactions (Chemical Society Reviews (2011) 40 (3430-3444) (DOI: 10.1039/c1cs15029d))

Chemical Society Reviews
2011 | Journal article
EID:

2-s2.0-81455144590

Part of ISSN: 14604744 03060012
Contributors: Domínguez, G.; Pérez-Castells, J.
Source: Self-asserted source
GEMA DOMINGUEZ MARTIN via Scopus - Elsevier

Recent advances in [2+2+2] cycloaddition reactions

Chemical Society Reviews
2011 | Journal article
EID:

2-s2.0-79957713071

Part of ISSN: 14604744 03060012
Contributors: Domínguez, G.; Pérez-Castells, J.
Source: Self-asserted source
GEMA DOMINGUEZ MARTIN via Scopus - Elsevier

Anomalous metathesis reactions of 3,4-disubstituted indoles

Arkivoc
2010 | Other
EID:

2-s2.0-77953414967

Part of ISSN: 15517004 15517012
Contributors: Pérez-Serrano, L.; Domínguez, G.; Pérez-Castells, J.
Source: Self-asserted source
GEMA DOMINGUEZ MARTIN via Scopus - Elsevier

Morita-Baylis-Hillman reaction of lactams and lactones with alkyl halides and epoxides catalyzed by hydroxysulfides

Organic Letters
2010 | Journal article
EID:

2-s2.0-77952412961

Part of ISSN: 15237060 15237052
Contributors: Suarez Del Villar, I.; Gradillas, A.; Domínguez, G.; Pérez-Castells, J.
Source: Self-asserted source
GEMA DOMINGUEZ MARTIN via Scopus - Elsevier

Nitrogen ylide-mediated cyclopropanation of lactams and lactones

Tetrahedron Letters
2010 | Journal article
EID:

2-s2.0-77953102927

Part of ISSN: 00404039
Contributors: Villar, I.S.d.; Gradillas, A.; Domínguez, G.; Pérez-Castells, J.
Source: Self-asserted source
GEMA DOMINGUEZ MARTIN via Scopus - Elsevier

Ruthenium carbene mediated [2+2+2] cyclotrimerizations

Synlett
2010 | Journal article
EID:

2-s2.0-77956016265

Part of ISSN: 09365214 14372096
Contributors: Mallagaray, Á.; Medina, S.; Domínguez, G.; Pérez-Castells, J.
Source: Self-asserted source
GEMA DOMINGUEZ MARTIN via Scopus - Elsevier

Discovering a new analogue of thalidomide which may be used as a potent modulator of TNF-α production

European Journal of Medicinal Chemistry
2009 | Journal article
EID:

2-s2.0-67650447754

Part of ISSN: 02235234 17683254
Contributors: Braña, M.F.; Acero, N.; Añorbe, L.; Mingarro, D.M.; Llinares, F.; Domínguez, G.
Source: Self-asserted source
GEMA DOMINGUEZ MARTIN via Scopus - Elsevier

Novel chemistry of β-carbolines. Expedient synthesis of polycyclic scaffolds

Tetrahedron
2009 | Journal article
EID:

2-s2.0-62849085967

Part of ISSN: 00404020
Contributors: González-Gómez, A.; Domínguez, G.; Pérez-Castells, J.
Source: Self-asserted source
GEMA DOMINGUEZ MARTIN via Scopus - Elsevier

Synthesis of benzazepines by gold-catalysed reactions of N-allenylamides

European Journal of Organic Chemistry
2009 | Journal article
EID:

2-s2.0-70349772076

Part of ISSN: 10990690 1434193X
Contributors: González-Gómez, Á.; Domínguez, G.; Pérez-Castells, J.
Source: Self-asserted source
GEMA DOMINGUEZ MARTIN via Scopus - Elsevier

An efficient catalytic protocol for the Pauson-Khand reaction

Tetrahedron
2008 | Journal article
EID:

2-s2.0-36448977676

Part of ISSN: 00404020
Contributors: Blanco-Urgoiti, J.; Abdi, D.; Domínguez, G.; Pérez-Castells, J.
Source: Self-asserted source
GEMA DOMINGUEZ MARTIN via Scopus - Elsevier

Chemistry of biologically active β-carbolines

Targets in Heterocyclic Systems
2008 | Book
EID:

2-s2.0-84987964471

Part of ISSN: 17249449
Contributors: Rosillo, M.; González-Gómez, A.; Domínguez, G.; Pérez-Castells, J.
Source: Self-asserted source
GEMA DOMINGUEZ MARTIN via Scopus - Elsevier

Combination of RCM and the Pauson-Khand reaction: One-step synthesis of tricyclic structures

European Journal of Organic Chemistry
2008 | Journal article
EID:

2-s2.0-53849100033

Part of ISSN: 1434193X 10990690
Contributors: Rosillo, M.; Arnáiz, E.; Abdi, D.; Blanco-Urgoiti, J.; Domínguez, G.; Pérez-Castells, J.
Source: Self-asserted source
GEMA DOMINGUEZ MARTIN via Scopus - Elsevier

Construction of quaternary centres for natural polycycles: The Pauson-Khand approach

Journal of Organometallic Chemistry
2008 | Journal article
EID:

2-s2.0-46549083151

Part of ISSN: 0022328X
Contributors: Arnáiz, E.; Blanco-Urgoiti, J.; Abdi, D.; Domínguez, G.; Castells, J.P.
Source: Self-asserted source
GEMA DOMINGUEZ MARTIN via Scopus - Elsevier

Intermolecular and intramolecular pauson-khand reactions of functionalized Allenes

European Journal of Organic Chemistry
2008 | Journal article
EID:

2-s2.0-53849098415

Part of ISSN: 1434193X 10990690
Contributors: González-Gómez, Á.; Añorbe, L.; Poblador, A.; Domínguez, G.; Pérez-Castells, J.
Source: Self-asserted source
GEMA DOMINGUEZ MARTIN via Scopus - Elsevier

Novel domino reactions in β-carbolines with triple bonded dienophiles

Tetrahedron Letters
2008 | Journal article
EID:

2-s2.0-48749086214

Part of ISSN: 00404039
Contributors: González-Gómez, A.; Domínguez, G.; Amador, U.; Pérez-Castells, J.
Source: Self-asserted source
GEMA DOMINGUEZ MARTIN via Scopus - Elsevier

Tandem RCM-lsomerization-cyclopropanation reactions

Organic Letters
2008 | Journal article
EID:

2-s2.0-39749140200

Part of ISSN: 15237060
Contributors: Mallagaray, Á.; Domínguez, G.; Gradillas, A.; Pérez-Castells, J.
Source: Self-asserted source
GEMA DOMINGUEZ MARTIN via Scopus - Elsevier

Chromium arene complexes in organic synthesis

Chemical Society Reviews
2007 | Journal article
EID:

2-s2.0-34548190967

Part of ISSN: 14604744 03060012
Contributors: Rosillo, M.; Domínguez, G.; Pérez-Castells, J.
Source: Self-asserted source
GEMA DOMINGUEZ MARTIN via Scopus - Elsevier

Arene-chromium tricarbonyl complexes in the Pauson-Khand reaction

Journal of Organic Chemistry
2005 | Journal article
EID:

2-s2.0-28744452663

Part of ISSN: 00223263
Contributors: Rosillo, M.; Domínguez, G.; Casarrubios, L.; Pérez-Castells, J.
Source: Self-asserted source
GEMA DOMINGUEZ MARTIN via Scopus - Elsevier

Enyne and dienyne metathesis reactions in β-carbolines

Tetrahedron Letters
2005 | Journal article
EID:

2-s2.0-24944465022

Part of ISSN: 00404039
Contributors: González-Gómez, A.; Domínguez, G.; Castells, J.P.
Source: Self-asserted source
GEMA DOMINGUEZ MARTIN via Scopus - Elsevier

Molecular sieves as promoters for the catalytic pauson-khand reaction

Catalysts for Fine Chemical Synthesis: Metal Catalysed Carbon-Carbon Bond-Forming Reactions
2005 | Book chapter
EID:

2-s2.0-85050208505

Contributors: Blanco-Urgoiti, J.; Domínguez, G.; Pérez-Castells, J.
Source: Self-asserted source
GEMA DOMINGUEZ MARTIN via Scopus - Elsevier

New approach indole alkaloids based on the intramolecular Pauson-Khand reaction

Journal of Organic Chemistry
2004 | Journal article
EID:

2-s2.0-3543047972

Part of ISSN: 00223263
Contributors: Pérez-Serrano, L.; Domínguez, G.; Pérez-Castells, J.
Source: Self-asserted source
GEMA DOMINGUEZ MARTIN via Scopus - Elsevier

New regio and stereoselective intermolecular Pauson-Khand reactions of allenamides

Tetrahedron Letters
2004 | Journal article
EID:

2-s2.0-2342646001

Part of ISSN: 00404039
Contributors: Añorbe, L.; Poblador, A.; Domínguez, G.; Pérez-Castells, J.
Source: Self-asserted source
GEMA DOMINGUEZ MARTIN via Scopus - Elsevier

Reorganization of enynes catalyzed by platinum salts

Chemistry - A European Journal
2004 | Journal article
EID:

2-s2.0-7044260985

Part of ISSN: 09476539
Contributors: Añorbe, L.; Domínguez, G.; Pérez-Castells, J.
Source: Self-asserted source
GEMA DOMINGUEZ MARTIN via Scopus - Elsevier

Tandem Enyne Metathesis-Diels-Alder Reaction for Construction of Natural Product Frameworks

Journal of Organic Chemistry
2004 | Journal article
EID:

2-s2.0-12144288301

Part of ISSN: 00223263
Contributors: Rosillo, M.; Domínguez, G.; Casarrubios, L.; Amador, U.; Pérez-Castells, J.
Source: Self-asserted source
GEMA DOMINGUEZ MARTIN via Scopus - Elsevier
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