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Keywords

Organocatalyst, Enantioselective Catalysis, Asymmetric Synthesis, Catalysis

Countries

Japan

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Employment (3)

Tohoku University: Sendai, JP

2006-04-01 to present | Professor (Department of Chemistry)
Employment
Source: Self-asserted source
Masahiro Terada

Tohoku University: Sendai, JP

2001-07-01 to 2006-03-31 | Associate Professor (Department of Chemistry)
Employment
Source: Self-asserted source
Masahiro Terada

Tokyo Institute of Technology: Tokyo, JP

1989-04-01 to 2001-06-30 | Assistant Professor (Deaptment of Applied Chemistry )
Employment
Source: Self-asserted source
Masahiro Terada

Education and qualifications (1)

Tokyo Institute of Technology: Tokyo, JP

1982-04-01 to 1989-03-31 | PhD (Applied Chemistry)
Education
Source: Self-asserted source
Masahiro Terada

Works (50 of 86)

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Page 1 of 2

Chiral Brønsted acid-catalysed enantioselective allylboration of sterically hindered aldehydes enabled by multiple hydrogen bonding interactions

Chemical Science
2025 | Journal article
DOI: 10.1039/D4SC08443H
Contributors: Shigenobu Umemiya; Sotaro Osaka; Naoya Shinagawa; Takumi Hirata; Masahiro Terada
Source: check_circle
Crossref

Phosphazene base-catalyzed telescopic three-component reaction involving 1,1-difunctionalization of electron-deficient alkenes

Chemical Communications
2025 | Journal article
DOI: 10.1039/D4CC05169F
Contributors: Azusa Kondoh; Sho Yamaguchi; Masahiro Terada
Source: check_circle
Crossref

Consecutive π-Lewis acidic metal-catalysed cyclisation/photochemical radical addition promoted by in situ generated 2-benzopyrylium as the photoredox catalyst

Chemical Science
2024 | Journal article
DOI: 10.1039/D4SC00808A
Contributors: Masahiro Terada; Ryohei Yazaki; Ren Obayashi; Zen Iwasaki; Shigenobu Umemiya; Jun Kikuchi
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Crossref

DFT calculation-aided optimisation of a chiral phosphoric acid catalyst: case study of kinetic resolution of racemic secondary alcohols through lactonisation

Catalysis Science & Technology
2024 | Journal article
DOI: 10.1039/D4CY01029A
Contributors: Haiting Ye; Takuma Sato; Taishi Nakanishi; Shigetomo Ito; Shigenobu Umemiya; Masahiro Terada
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Crossref

Optoelectronic characteristics of furan substituted thiophene/phenylene co-oligomer single crystals for organic lasing

Journal of Materials Chemistry C
2024 | Journal article
DOI: 10.1039/D4TC03149K
Contributors: Periyasamy Angamuthu Praveen; Thangavel Kanagasekaran; Chaoyan Ma; Masahiro Terada; Tienan Jin; Yusuke Wakabayashi; Hidekazu Shimotani
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Crossref

Catalytic Generation of Benzyl Anions from Aryl Ketones Utilizing [1,2]‐Phospha‐Brook Rearrangement and Their Application to Synthesis of Tertiary Benzylic Alcohols

Chemistry – A European Journal
2024-12-10 | Journal article
DOI: 10.1002/chem.202402967
Contributors: Azusa Kondoh; Hirochika Suzuki; Takayuki Hirozane; Masahiro Terada
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Development of a flow photochemical process for a π-Lewis acidic metal-catalyzed cyclization/radical addition sequence: in situ-generated 2-benzopyrylium as photoredox catalyst and reactive intermediate

Beilstein Journal of Organic Chemistry
2024-08-13 | Journal article
DOI: 10.3762/bjoc.20.173
Contributors: Masahiro Terada; Zen Iwasaki; Ryohei Yazaki; Shigenobu Umemiya; Jun Kikuchi
Source: check_circle
Crossref

Asymmetric Auto-Tandem Catalysis with Chiral Organosuperbases: Intramolecular Cyclization/Enantioselective Direct Mannich-Type Addition Sequence

Organic Letters
2024-08-02 | Journal article
DOI: 10.1021/acs.orglett.4c02532
Contributors: Azusa Kondoh; Takuro Kato; Hao Chen; Masahiro Terada
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Crossref

Construction of 1,3‐Nonadjacent Stereogenic Centers Through Enantioselective Addition of α‐Thioacetamides to α‐Substituted Vinyl Sulfones Catalyzed by Chiral Strong Brønsted Base

Advanced Science
2024-03 | Journal article
DOI: 10.1002/advs.202308020
Contributors: Azusa Kondoh; Rihaku Ojima; Sho Ishikawa; Masahiro Terada
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Crossref

Computational molecular refinement to enhance enantioselectivity by reinforcing hydrogen bonding interactions in major reaction pathway

Chemical Science
2023 | Journal article
DOI: 10.1039/D3SC01637D
Contributors: Taishi Nakanishi; Masahiro Terada
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Copper-catalyzed [1,3]-nitrogen rearrangement of O-aryl ketoximes via oxidative addition of N–O bond in inverse electron flow

Chemical Science
2023 | Journal article
DOI: 10.1039/D3SC00874F
Contributors: Mao Suzuki; Masahiro Terada; Itaru Nakamura
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Crossref

Enantioselective direct Michael addition of cyanohydrin ether derivatives to enones catalyzed by chiral bis(guanidino)iminophosphorane organosuperbase

Chemical Science
2023 | Journal article
DOI: 10.1039/D2SC07065K
Contributors: Saikat Das; Azusa Kondoh; Masahiro Terada
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Crossref

Intermolecular exo-selective Diels–Alder reaction catalysed by dual-functional Brønsted acid: conformational restriction of transition states by hydrogen bonds as the key interaction

RSC Advances
2023 | Journal article
DOI: 10.1039/D3RA07688A
Contributors: Taishi Nakanishi; Masahiro Terada
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Crossref

Synthesis of Curved Polycyclic Arenes Embedded with Oxepine and Thiepine Using Ring Expansion Strategy

Organic Letters
2023-07-14 | Journal article
DOI: 10.1021/acs.orglett.3c01730
Contributors: Sheng Zhang; Hidenori Matsuyama; Itaru Nakamura; Masahiro Terada; Tienan Jin
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Crossref

Formal Addition of β‐Acylalkenyl Anions to Ketones Utilizing [1,2]‐Phospha‐Brook Rearrangement under Brønsted Base Catalysis

European Journal of Organic Chemistry
2023-07-03 | Journal article
DOI: 10.1002/ejoc.202300425
Contributors: Azusa Kondoh; Sena Takada; Kohei Aita; Masahiro Terada
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Crossref

Synthesis of Polysubstituted Naphthofurans and Indenofurans Based on a Regiodivergent Intramolecular Carbometalation Strategy with 2‐(2’‐Alkynylaryl)‐3‐iodofurans

Chemistry – A European Journal
2023-05-02 | Journal article
DOI: 10.1002/chem.202300132
Contributors: Azusa Kondoh; Kohei Aita; Masahiro Terada
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Crossref

[1,2]‐Phospha‐Brook Rearrangement as Tool for Generation of Anionic Nucleophiles in Addition Reactions under Brønsted Base Catalysis

Asian Journal of Organic Chemistry
2023-03 | Journal article
DOI: 10.1002/ajoc.202300003
Contributors: Azusa Kondoh; Masahiro Terada
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Crossref

Scalable Total Synthesis of Leucascandrolide A Macrolactone Using a Chiral Phosphoric Acid/CuX Combined Catalytic System

Organic Letters
2023-03-24 | Journal article
DOI: 10.1021/acs.orglett.3c00450
Contributors: Shigenobu Umemiya; Naoya Shinagawa; Masahiro Terada
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Crossref

Construction of Alkylidene Fluorene Scaffolds Using Pd-Catalyzed Direct Arene/Alkene Coupling Strategy

Organic Letters
2023-02-10 | Journal article
DOI: 10.1021/acs.orglett.2c04307
Contributors: Hidenori Matsuyama; Xuan Zhang; Masahiro Terada; Tienan Jin
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Crossref

Brønsted base-catalyzed 1,2-addition/[1,2]-phospha-Brook rearrangement sequence providing functionalized phosphonates

Organic & Biomolecular Chemistry
2022 | Journal article
DOI: 10.1039/D2OB00256F
Contributors: Azusa Kondoh; Masahiro Terada
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Crossref

Kinetic resolution of racemic tertiary allylic alcohols through SN2′ reaction using a chiral bisphosphoric acid/silver(i) salt co-catalyst system

Chemical Science
2022 | Journal article
DOI: 10.1039/D2SC03052G
Contributors: Satavisha Kayal; Jun Kikuchi; Naoya Shinagawa; Shigenobu Umemiya; Masahiro Terada
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Crossref

Gold-Catalyzed Intermolecular Alkyne Insertion into the N–S Bond in Sulfenamides

Organic Letters
2022-12-23 | Journal article
DOI: 10.1021/acs.orglett.2c03831
Contributors: Takato Asoh; Hiroki Tashiro; Masahiro Terada; Itaru Nakamura
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Crossref

Brønsted Base Catalyzed Conjugate Addition of β-Acylvinyl Anion Equivalents to α,β-Unsaturated Ketones

Synlett
2022-11 | Journal article
DOI: 10.1055/a-1827-5652
Contributors: Azusa Kondoh; Masahiro Terada; Sho Yamaguchi; Yushi Watanabe
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Crossref

Iridium-Catalyzed Double Asymmetric Hydrogenation of 2,5-Dialkylienecyclopentanones for the Synthesis of Chiral Cyclopentanones

Organic Letters
2022-11-04 | Journal article
DOI: 10.1021/acs.orglett.2c02656
Contributors: Yu Nie; Qianjia Yuan; Feng Gao; Masahiro Terada; Wanbin Zhang
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Synthesis of 2,2‐Disubstituted 2H‐Chromenes through Carbon‐Carbon Bond Formation Utilizing a [1,2]‐Phospha‐Brook Rearrangement under Brønsted Base Catalysis

Chemistry – A European Journal
2022-08-10 | Journal article
DOI: 10.1002/chem.202201198
Contributors: Azusa Kondoh; Masahiro Terada
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Crossref

Formal Umpolung Addition of Phosphites to 2‐Azaaryl Ketones under Chiral Brønsted Base Catalysis: Enantioselective Protonation Utilizing [1,2]‐Phospha‐Brook Rearrangement

Chemistry – A European Journal
2022-07-26 | Journal article
DOI: 10.1002/chem.202201240
Contributors: Azusa Kondoh; Takayuki Hirozane; Masahiro Terada
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Crossref

Copper-catalyzed [1,3]-alkoxy rearrangement for the selective synthesis of polycyclic ortho-aminoarenol derivatives

Organic Chemistry Frontiers
2021 | Journal article
DOI: 10.1039/D1QO01189H
Contributors: Itaru Nakamura; Satoru Nozawa; Yasuhiro Ishida; Ichiro Muranushi; Alexandra Mayerweg; Masahiro Terada
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Crossref

Dynamic parallel kinetic resolution of α-ferrocenyl cation initiated by chiral Brønsted acid catalyst

Chemical Science
2021 | Journal article
DOI: 10.1039/D1SC02122B
Contributors: Yasunori Toda; Toshinobu Korenaga; Ren Obayashi; Jun Kikuchi; Masahiro Terada
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Crossref

Radical addition reaction between chromenols and toluene derivatives initiated by Brønsted acid catalyst under light irradiation

Organic Chemistry Frontiers
2021 | Journal article
DOI: 10.1039/D1QO00657F
Contributors: Jun Kikuchi; Shota Kodama; Masahiro Terada
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Crossref

Pd-Catalyzed Indolization/peri-C–H Annulation/N-Dealkylation Cascade to Cyclopenta-Fused Acenaphtho[1,2-b]indole Scaffold

Organic Letters
2021-12-17 | Journal article
DOI: 10.1021/acs.orglett.1c03575
Contributors: Tienan Jin; Shin Suzuki; Hon Eong Ho; Hidenori Matsuyama; Masaki Kawata; Masahiro Terada
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Crossref

Formal Fluorinative Ring Opening of 2-Benzoylpyrrolidines Utilizing [1,2]-Phospha-Brook Rearrangement for Synthesis of 2-Aryl-3-fluoropiperidines

Organic Letters
2021-10-15 | Journal article
DOI: 10.1021/acs.orglett.1c02907
Contributors: Azusa Kondoh; Rihaku Ojima; Masahiro Terada
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Crossref

Correction to “Chiral Brønsted Acid-Catalyzed Formal α-Vinylation of Cyclopentanones for the Enantioselective Construction of Quaternary Carbon Centers”

ACS Catalysis
2021-07-16 | Journal article
DOI: 10.1021/acscatal.1c02714
Contributors: Satavisha Kayal; Jun Kikuchi; Masahiro Shimizu; Naoya Shinagawa; Shigenobu Umemiya; Masahiro Terada
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Crossref

Cu-Catalyzed [1,3]-Alkoxy Rearrangement/Diels–Alder Cascade Reactions via in Situ Generation of Functionalized ortho-Quinol Imines

Organic Letters
2021-06-04 | Journal article
DOI: 10.1021/acs.orglett.1c00995
Contributors: Itaru Nakamura; Kazuki Masukawa; Yasuhiro Ishida; Masahiro Terada
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Crossref

Catalytic Enantioselective Allylation of Acetylenic Aldehydes by Chiral Phosphoric Acid/Transition Metal Cooperative Catalysis: Formal Synthesis of Fostriecin

Organic Letters
2021-05-07 | Journal article
DOI: 10.1021/acs.orglett.1c01166
Contributors: Shigenobu Umemiya; Masahiro Terada
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Crossref

Enantioselective Protonation: Hydrophosphinylation of 1,1‐Vinyl Azaheterocycle N‐Oxides Catalyzed by Chiral Bis(guanidino)iminophosphorane Organosuperbase

Angewandte Chemie
2021-01-18 | Journal article
DOI: 10.1002/ange.202012492
Contributors: Saikat Das; Qiupeng Hu; Azusa Kondoh; Masahiro Terada
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Crossref

Enantioselective Protonation: Hydrophosphinylation of 1,1‐Vinyl Azaheterocycle N‐Oxides Catalyzed by Chiral Bis(guanidino)iminophosphorane Organosuperbase

Angewandte Chemie International Edition
2021-01-18 | Journal article
DOI: 10.1002/anie.202012492
Contributors: Saikat Das; Qiupeng Hu; Azusa Kondoh; Masahiro Terada
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Crossref

Brønsted Base‐Catalyzed Formal Reductive [3+2] Annulation of 4,4,4‐Trifluorocrotonate and α‐Iminoketones

Chemistry – A European Journal
2021-01-07 | Journal article
DOI: 10.1002/chem.202002943
Contributors: Azusa Kondoh; Masahiro Terada
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Crossref

Chiral strong Brønsted acid-catalyzed enantioselective addition reaction of simple olefins with ethyl glyoxylate

Organic Chemistry Frontiers
2020 | Journal article
DOI: 10.1039/D0QO00448K
Contributors: Jun Kikuchi; Yuki Aizawa; Masahiro Terada
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Crossref

Enantioselective hydrophosphinylation of 1-alkenylphosphine oxides catalyzed by chiral strong Brønsted base

Organic & Biomolecular Chemistry
2020 | Journal article
DOI: 10.1039/D0OB01778G
Contributors: Azusa Kondoh; Sho Ishikawa; Masahiro Terada
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Crossref

Synthesis of diarylalkanes through an intramolecular/intermolecular addition sequence by auto-tandem catalysis with strong Brønsted base

Chemical Communications
2020 | Journal article
DOI: 10.1039/D0CC04512H
Contributors: Azusa Kondoh; Chaoyan Ma; Masahiro Terada
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Crossref

Chiral Phosphoric Acid Catalyzed Enantioselective [4 + 2] Cycloaddition Reaction of α-Fluorostyrenes with Imines

Organic Letters
2020-11-20 | Journal article
DOI: 10.1021/acs.orglett.0c03360
Contributors: Jun Kikuchi; Haiting Ye; Masahiro Terada
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Crossref

Chiral Phosphoric Acid-Catalyzed Enantioselective Phospha-Michael-Type Addition Reaction of Diarylphosphine Oxides with Alkenyl Benzimidazoles

The Journal of Organic Chemistry
2020-11-20 | Journal article
DOI: 10.1021/acs.joc.0c01840
Contributors: Linan Hou; Jun Kikuchi; Haiting Ye; Ming Bao; Masahiro Terada
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Crossref

Intermolecular Oxidative Friedel–Crafts Reaction Triggered Ring Expansion Affording 9,10-Diarylphenanthrenes

Organic Letters
2020-11-20 | Journal article
DOI: 10.1021/acs.orglett.0c03283
Contributors: Lu Yang; Ilya D. Gridnev; Masahiro Terada; Tienan Jin
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Crossref

Chiral Brønsted Acid Catalyzed Enantioconvergent Propargylic Substitution Reaction of Racemic Secondary Propargylic Alcohols with Thiols

Chemistry – A European Journal
2020-09 | Journal article
DOI: 10.1002/chem.202001609
Contributors: Jun Kikuchi; Kyohei Takano; Yusuke Ota; Shigenobu Umemiya; Masahiro Terada
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Crossref

Brønsted Base-Catalyzed Transformation of α,β-Epoxyketones Utilizing [1,2]-Phospha-Brook Rearrangement for the Synthesis of Allylic Alcohols Having a Tetrasubstituted Alkene Moiety

Organic Letters
2020-07-02 | Journal article
DOI: 10.1021/acs.orglett.0c01765
Contributors: Azusa Kondoh; Naoko Tasato; Takuma Aoki; Masahiro Terada
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Crossref

One‐Pot Synthesis of Enantioenriched β‐Amino Secondary Amides via an Enantioselective [4+2] Cycloaddition Reaction of Vinyl Azides with N‐Acyl Imines Catalyzed by a Chiral Brønsted Acid

Chemistry – A European Journal
2020-07-02 | Journal article
DOI: 10.1002/chem.202002049
Contributors: Taishi Nakanishi; Jun Kikuchi; Atsushi Kaga; Shunsuke Chiba; Masahiro Terada
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Crossref

Tandem Oxidative Ring Expansion for Synthesis of Dibenzocyclooctaphenanthrenes

Organic Letters
2020-07-02 | Journal article
DOI: 10.1021/acs.orglett.0c01725
Contributors: Lu Yang; Hidenori Matsuyama; Sheng Zhang; Masahiro Terada; Tienan Jin
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Crossref

Synthesis of meta-Substituted Anilines via Copper-Catalyzed [1,3]-Methoxy Rearrangement

Organic Letters
2020-05-15 | Journal article
DOI: 10.1021/acs.orglett.0c01009
Contributors: Itaru Nakamura; Hiroki Tashiro; Yasuhiro Ishida; Masahiro Terada
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Crossref

Development of Chiral Organosuperbase Catalysts Consisting of Two Different Organobase Functionalities

Angewandte Chemie
2020-05-04 | Journal article
DOI: 10.1002/ange.202001419
Contributors: Azusa Kondoh; Masafumi Oishi; Hikaru Tezuka; Masahiro Terada
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Crossref

Development of Chiral Organosuperbase Catalysts Consisting of Two Different Organobase Functionalities

Angewandte Chemie International Edition
2020-05-04 | Journal article
DOI: 10.1002/anie.202001419
Contributors: Azusa Kondoh; Masafumi Oishi; Hikaru Tezuka; Masahiro Terada
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Crossref
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Peer review (3 reviews for 2 publications/grants)

Review activity for Angewandte Chemie. (2)
Review activity for Journal of organic chemistry. (1)
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