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Geminal bimetallic coordination of a carbone to main-group and transition metals

Chemical Communications
2024 | Journal article
Part of ISSN: 1359-7345
Part of ISSN: 1364-548X
Contributors: Akachukwu Obi; Chun-Lin Deng; Andrew J. Alexis; Diane A. Dickie; Robert J. Gilliard
Source: Self-asserted source
Robert J. Gilliard, Jr.

Unlocking Biradical Character in Diborepins

Journal of the American Chemical Society
2024-02-29 | Journal article | Author
Part of ISSN: 0002-7863
Part of ISSN: 1520-5126
Contributors: Kimberly K. Hollister; Andrew Molino; Nula Jones; VuongVy V. Le; Diane A. Dickie; David Cafiso; David J D Wilson; Robert J. Gilliard, Jr.
Source: Self-asserted source
Robert J. Gilliard, Jr.

Unveiling Three Interconvertible Redox States of Boraphenalene

Journal of the American Chemical Society
2024-02-21 | Journal article | Author
Part of ISSN: 0002-7863
Part of ISSN: 1520-5126
Contributors: Chun-Lin Deng; Kimberly K. Hollister; Andrew Molino; Bi Youan E. Tra; Diane A. Dickie; David J D Wilson; Robert J. Gilliard, Jr.
Source: Self-asserted source
Robert J. Gilliard, Jr.

Solvatochromic and aggregation-induced emission active nitrophenyl-substituted pyrrolidinone-fused-1,2-azaborine with a pre-twisted molecular geometry

Journal of Materials Chemistry C
2023 | Journal article
Part of ISSN: 2050-7526
Part of ISSN: 2050-7534
Contributors: Albert D. Campbell Jr.; Kaia Ellis; Lyric K. Gordon; Janiyah E. Riley; VuongVy V. Le; Kimberly K. Hollister; Stephen Ajagbe ; Samer Gozem; Robert B. Hughley; Adeline M. Boswell et al.
Source: Self-asserted source
Robert J. Gilliard, Jr.

Air- and photo-stable luminescent carbodicarbene-azaboraacenium ions

Nature Chemistry
2023-12-05 | Journal article | Author
Part of ISSN: 1755-4330
Part of ISSN: 1755-4349
Contributors: Chun-Lin Deng; Akachukwu D. Obi; Bi Youan E. Tra; SAMIR KUMAR SARKAR; Diane A. Dickie; Robert J. Gilliard, Jr.
Source: Self-asserted source
Robert J. Gilliard, Jr.

Bis(9-Boraphenanthrene) and Its Stable Biradical

Journal of the American Chemical Society
2023-10-04 | Journal article | Author
Part of ISSN: 0002-7863
Part of ISSN: 1520-5126
Contributors: Samir Kumar Sarkar; Kimberly K. Hollister; Andrew Molino; Akachukwu D. Obi; Chun-Lin Deng; Bi Youan E. Tra; Brennan M. Stewart; Diane A. Dickie; David J D Wilson; Robert J. Gilliard, Jr.
Source: Self-asserted source
Robert J. Gilliard, Jr.

Photochemically and Thermally Generated BN-Doped Borafluorenate Heterocycles via Intramolecular Staudinger-Type Reactions

Inorganic Chemistry
2023-10-02 | Journal article | Author
Part of ISSN: 0020-1669
Part of ISSN: 1520-510X
Contributors: Bi Youan E. Tra; Andrew Molino; Kimberly K. Hollister; Samir Kumar Sarkar; Diane A. Dickie; David J D Wilson; Robert J. Gilliard, Jr.
Source: Self-asserted source
Robert J. Gilliard, Jr.

Boron-Doped Pentacenes: Isolation of Crystalline 5,12- and 5,7-Diboratapentacene Dianions

Journal of the American Chemical Society
2023-02-01 | Journal article | Author
Part of ISSN: 0002-7863
Part of ISSN: 1520-5126
Contributors: Joshua Barker; Akachukwu Obi; Diane A. Dickie; Robert J. Gilliard, Jr.
Source: Self-asserted source
Robert J. Gilliard, Jr.

Approaching Dianionic Tetraoxadiborecine Macrocycles: 10‐Membered Bora‐Crown Ethers Incorporating Borafluorenate Units

Angewandte Chemie International Edition
2023-01-26 | Journal article | Author
Part of ISSN: 1433-7851
Part of ISSN: 1521-3773
Contributors: Kelsie Wentz; Andrew Molino; Lucas Freeman; Diane A. Dickie; David J D Wilson; Robert J. Gilliard, Jr.
Source: Self-asserted source
Robert J. Gilliard, Jr.

A Multidimensional Approach to Carbodiphosphorane–Bismuth Coordination Chemistry: Cationization, Redox-Flexibility, and Stabilization of a Crystalline Bismuth Hydridoborate

Inorganic Chemistry
2022-12-05 | Journal article | Author
Part of ISSN: 0020-1669
Part of ISSN: 1520-510X
Contributors: Akachukwu Obi; Diane A. Dickie; William Tiznado; Gernot Frenking; Sudip Pan; Robert J. Gilliard, Jr.
Source: Self-asserted source
Robert J. Gilliard, Jr.

Lewis Superacidic Heavy Pnictaalkene Cations: Comparative Assessment of Carbodicarbene-Stibenium and Carbodicarbene-Bismuthenium Ions

Inorganic Chemistry
2022-11-21 | Journal article | Author
Part of ISSN: 0020-1669
Part of ISSN: 1520-510X
Contributors: Levi Warring; Jacob E. Walley; Diane A. Dickie; William Tiznado; sudip pan; Robert J. Gilliard, Jr.
Source: Self-asserted source
Robert J. Gilliard, Jr.

Carbene–Calcium Silylamides and Amidoboranes

Organometallics
2022-11-14 | Journal article | Author
Part of ISSN: 0276-7333
Part of ISSN: 1520-6041
Contributors: Akachukwu Obi; Lucas Freeman; Samuel J. Coates; Andrew J. H. Alexis; Nathan C. Frey; Diane A. Dickie; Charles Edwin Webster; Robert J. Gilliard, Jr.
Source: Self-asserted source
Robert J. Gilliard, Jr.

Systematic Electronic and Structural Studies of 9-Carbene-9-Borafluorene Monoanions and Transformations into Luminescent Boron Spirocycles

Inorganic Chemistry
2022-10-31 | Journal article | Author
Part of ISSN: 0020-1669
Part of ISSN: 1520-510X
Contributors: Kelsie Wentz; Andrew Molino; Lucas Freeman; Diane A. Dickie; David J D Wilson; Robert J. Gilliard, Jr.
Source: Self-asserted source
Robert J. Gilliard, Jr.

N‐Heterocyclic Carbene‐Assisted Reversible Migratory Coupling of Aminoborane at Magnesium

Angewandte Chemie International Edition
2022-10-24 | Journal article | Author
Part of ISSN: 1433-7851
Part of ISSN: 1521-3773
Contributors: Akachukwu Obi; Nathan C. Frey; Diane A. Dickie; Charles Edwin Webster; Robert J. Gilliard, Jr.
Source: Self-asserted source
Robert J. Gilliard, Jr.

Activation of Carbon Dioxide by 9-Carbene-9-borafluorene Monoanion: Carbon Monoxide Releasing Transformation of Trioxaborinanone to Luminescent Dioxaborinanone

Journal of the American Chemical Society
2022-09-14 | Journal article | Author
Part of ISSN: 0002-7863
Part of ISSN: 1520-5126
Contributors: Kelsie Wentz; Andrew Molino; Lucas Freeman; Diane A. Dickie; David J D Wilson; Robert J. Gilliard, Jr.
Source: Self-asserted source
Robert J. Gilliard, Jr.

Isolation of Stable Borepin Radicals and Anions

Angewandte Chemie International Edition
2022-06-07 | Journal article | Author
Part of ISSN: 1433-7851
Part of ISSN: 1521-3773
Contributors: Kimberly Hollister; wenlong yang; Dr. Ranajit Mondol; Kelsie Wentz; Andrew Molino; Aishvaryadeep Kaur; Diane A. Dickie; Gernot Frenking; sudip pan; David J D Wilson et al.
Source: Self-asserted source
Robert J. Gilliard, Jr.

Synthesis and reactivity of low-oxidation-state alkaline earth metal complexes

Nature Synthesis
2022-06-02 | Journal article | Author
Part of ISSN: 2731-0582
Contributors: Lucas Freeman; Jacob E. Walley; Robert J. Gilliard, Jr.
Source: Self-asserted source
Robert J. Gilliard, Jr.

Air-Stable Thermoluminescent Carbodicarbene-Borafluorenium Ions

Journal of the American Chemical Society
2022-01-12 | Journal article | Author
Part of ISSN: 0002-7863
Part of ISSN: 1520-5126
Contributors: Kimberly Hollister; Andrew Molino; Grace Breiner; Jacob E. Walley; Kelsie Wentz; Ashley M. Conley; Diane A. Dickie; David J D Wilson; Robert J. Gilliard, Jr.
Source: Self-asserted source
Robert J. Gilliard, Jr.

Soluble, crystalline, and thermally stable alkali CO<sub>2</sub><sup>−</sup> and carbonite (CO<sub>2</sub><sup>2−</sup>) clusters supported by cyclic(alkyl)(amino) carbenes

Chemical Science
2021 | Journal article | Author
Part of ISSN: 2041-6520
Part of ISSN: 2041-6539
Contributors: Lucas Freeman; Akachukwu Obi; Haleigh Machost; Andrew Molino; Asa W. Nichols; Diane A. Dickie; David J D Wilson; Charles Machan; Robert J. Gilliard, Jr.
Source: Self-asserted source
Robert J. Gilliard, Jr.

Recent Adventures in Beryllium Chemistry

Encyclopedia of Inorganic and Bioinorganic Chemistry
2021-10-26 | Other
Contributors: Jacob E. Walley; Robert J. Gilliard
Source: Self-asserted source
Robert J. Gilliard, Jr.

Reactions of 9-Carbene-9-Borafluorene Monoanion and Selenium: Synthesis of Boryl-Substituted Selenides and Diselenides

Inorganic Chemistry
2021-09-20 | Journal article | Author
Part of ISSN: 0020-1669
Part of ISSN: 1520-510X
Contributors: Kelsie Wentz; Andrew Molino; Lucas Freeman; Diane A. Dickie; David J D Wilson; Robert J. Gilliard, Jr.
Source: Self-asserted source
Robert J. Gilliard, Jr.

A Thermally Stable Magnesium Phosphaethynolate Grignard Complex

Inorganic Chemistry
2021-08-16 | Journal article | Author
Part of ISSN: 0020-1669
Part of ISSN: 1520-510X
Contributors: Akachukwu Obi; Haleigh R. Machost; Diane A. Dickie; Robert J. Gilliard, Jr.
Source: Self-asserted source
Robert J. Gilliard, Jr.

Stabilization of the Elusive 9‐Carbene‐9‐Borafluorene Monoanion

Angewandte Chemie International Edition
2021-06 | Journal article | Author
Part of ISSN: 1433-7851
Part of ISSN: 1521-3773
Contributors: Kelsie E. Wentz; Andrew Molino; Sarah L. Weisflog; Aishvaryadeep Kaur; Diane A. Dickie; David J. D. Wilson; Robert J. Gilliard, Jr.
Source: Self-asserted source
Robert J. Gilliard, Jr.

s‐Block Multiple Bonds: Isolation of a Beryllium Imido Complex

Angewandte Chemie International Edition
2021-04-19 | Journal article | Author
Part of ISSN: 1433-7851
Part of ISSN: 1521-3773
Contributors: Guocang Wang; Jacob E. Walley; Diane A. Dickie; Andrew Molino; David J. D. Wilson; Robert J. Gilliard, Jr.
Source: Self-asserted source
Robert J. Gilliard, Jr.

Indirect Access to Carbene Adducts of Bismuth- and Antimony-Substituted Phosphaketene and Their Unusual Thermal Transformation to Dipnictines and [(NHC)<sub>2</sub>OCP][OCP]

Inorganic Chemistry
2021-04-05 | Journal article | Author
Part of ISSN: 0020-1669
Part of ISSN: 1520-510X
Contributors: Jacob E. Walley; Levi S. Warring; Erik Kertész; guocang wang; Diane A. Dickie; Zoltán Benkő; Robert J. Gilliard, Jr.
Source: Self-asserted source
Robert J. Gilliard, Jr.

Carbodicarbene Bismaalkene Cations: Unravelling the Complexities of Carbene versus Carbone in Heavy Pnictogen Chemistry

Angewandte Chemie International Edition
2021-03-15 | Journal article | Author
Part of ISSN: 1433-7851
Part of ISSN: 1521-3773
Contributors: Jacob E. Walley; Levi S. Warring; Guocang Wang; Diane A. Dickie; Sudip Pan; Gernot Frenking; Robert J. Gilliard, Jr.
Source: Self-asserted source
Robert J. Gilliard, Jr.

Surfactant Removal for Colloidal Nanocrystal Catalysts Mediated by N-Heterocyclic Carbenes

Journal of the American Chemical Society
2021-02-24 | Journal article | Author
Part of ISSN: 0002-7863
Part of ISSN: 1520-5126
Contributors: Perrin Godbold; Grayson Johnson; Akachukwu D. Obi; Rebecca Brown; Sooyeon Hwang; Robert J. Gilliard, Jr.; Sen Zhang
Source: Self-asserted source
Robert J. Gilliard, Jr.

N-Heterocyclic Carbene-Mediated Ring Opening of Reduced Diazamagnesacycles

Organometallics
2020-12-28 | Journal article | Author
Part of ISSN: 0276-7333
Part of ISSN: 1520-6041
Contributors: Akachukwu D. Obi; Lucas Freeman; Diane A. Dickie; Robert J. Gilliard, Jr.
Source: Self-asserted source
Robert J. Gilliard, Jr.

An Update on the “Organometallic Chemistry of the Main-Group Elements”

Organometallics
2020-12-14 | Journal article | Author
Part of ISSN: 0276-7333
Part of ISSN: 1520-6041
Contributors: Robert J. Gilliard, Jr.; CHING-WEN CHIU
Source: Self-asserted source
Robert J. Gilliard, Jr.

Tris(carbene) Stabilization of Monomeric Magnesium Cations: A Neutral, Nontethered Ligand Approach

Organometallics
2020-12-14 | Journal article | Author
Part of ISSN: 0276-7333
Part of ISSN: 1520-6041
Contributors: Akachukwu Obi; Jacob E. Walley; Nathan C. Frey; Yuen Onn Wong; Diane A. Dickie; Charles Edwin Webster; Robert J. Gilliard, Jr.
Source: Self-asserted source
Robert J. Gilliard, Jr.

Planar, Stair‐Stepped, and Twisted: Modulating Structure and Photophysics in Pyrene‐ and Benzene‐Fused N‐Heterocyclic Boranes

Chemistry – A European Journal
2020-08-06 | Journal article | Author
Part of ISSN: 0947-6539
Part of ISSN: 1521-3765
Contributors: Kelsie Wentz; Sarah Weisflog; Nathan C. Frey; wenlong yang; Diane A. Dickie; Charles Edwin Webster; Robert J. Gilliard, Jr.
Source: Self-asserted source
Robert J. Gilliard, Jr.

Crystallographic study of a heteroleptic chloroberyllium borohydride carbodicarbene complex

Zeitschrift für Naturforschung B
2020-05-26 | Journal article | Author
Part of ISSN: 1865-7117
Part of ISSN: 0932-0776
Contributors: Jacob E. Walley; Diane A. Dickie; Robert J. Gilliard, Jr.
Source: Self-asserted source
Robert J. Gilliard, Jr.

A Stable, Crystalline Beryllium Radical Cation

Journal of the American Chemical Society
2020-03-11 | Journal article | Author
Part of ISSN: 0002-7863
Part of ISSN: 1520-5126
Contributors: guocang wang; Jacob E. Walley; Diane A. Dickie; sudip pan; Gernot Frenking; Robert J. Gilliard, Jr.
Source: Self-asserted source
Robert J. Gilliard, Jr.

Crystalline BP‐Doped Phenanthryne via Photolysis of The Elusive Boraphosphaketene

Angewandte Chemie International Edition
2020-03-02 | Journal article | Author
Part of ISSN: 1433-7851
Part of ISSN: 1521-3773
Contributors: wenlong yang; Kelsie Wentz; Diane A. Dickie; Andrew Molino; David J D Wilson; Robert J. Gilliard, Jr.
Source: Self-asserted source
Robert J. Gilliard, Jr.

Persistent Borafluorene Radicals

Angewandte Chemie International Edition
2020-03-02 | Journal article | Author
Part of ISSN: 1433-7851
Part of ISSN: 1521-3773
Contributors: Wenlong Yang; Kelsie Wentz; Lucas Freeman; Diane A. Dickie; Andrew Molino; Gernot Frenking; Sudip Pan; David J. D. Wilson; Robert J. Gilliard, Jr.
Source: Self-asserted source
Robert J. Gilliard, Jr.

Extremely twisted and bent pyrene-fused N-heterocyclic germylenes

Chemical Communications
2019 | Journal article | Author
Part of ISSN: 1359-7345
Part of ISSN: 1364-548X
Contributors: Kelsie Wentz; Sarah Weisflog; wenlong yang; Diane A. Dickie; Nathan C. Frey; Charles Edwin Webster; Robert J. Gilliard, Jr.
Source: Self-asserted source
Robert J. Gilliard, Jr.

Low-nuclearity magnesium hydride complexes stabilized by N-heterocyclic carbenes

Dalton Transactions
2019 | Journal article | Author
Part of ISSN: 1477-9226
Part of ISSN: 1477-9234
Contributors: Lucas Freeman; Jacob E. Walley; Diane A. Dickie; Robert J. Gilliard, Jr.
Source: Self-asserted source
Robert J. Gilliard, Jr.

s-Block carbodicarbene chemistry: C(sp3)–H activation and cyclization mediated by a beryllium center

2019 | Journal article
Part of ISSN: 1359-7345
Part of ISSN: 1364-548X
Source: Self-asserted source
Robert J. Gilliard, Jr.
grade
Preferred source (of 3)‎

N-Heterocyclic Carbene-Supported Aryl- and Alk- oxides of Beryllium and Magnesium

Catalysts
2019-11-08 | Journal article
Part of ISSN: 2073-4344
Contributors: Jacob E. Walley; Yuen-Onn Wong; Lucas A. Freeman; Diane A. Dickie; Robert J. Gilliard
Source: Self-asserted source
Robert J. Gilliard, Jr.

Stable Borepinium and Borafluorenium Heterocycles: A Reversible Thermochromic “Switch” Based on Boron–Oxygen Interactions

Chemistry – A European Journal
2019-09-25 | Journal article | Author
Part of ISSN: 0947-6539
Part of ISSN: 1521-3765
Contributors: Wenlong Yang; Kelsie E. Krantz; Lucas A. Freeman; Diane A. Dickie; Andrew Molino; Aishvaryadeep Kaur; David J. D. Wilson; Robert J. Gilliard, Jr.
Source: Self-asserted source
Robert J. Gilliard, Jr.

Cyclic(alkyl)(amino) Carbene-Promoted Ring Expansion of a Carbodicarbene Beryllacycle

Inorganic Chemistry
2019-08-19 | Journal article | Author
Part of ISSN: 0020-1669
Part of ISSN: 1520-510X
Contributors: Jacob E. Walley; Akachukwu D. Obi; Grace Breiner; guocang wang; Diane A. Dickie; Andrew Molino; Jason Dutton; David J D Wilson; Robert J. Gilliard, Jr.
Source: Self-asserted source
Robert J. Gilliard, Jr.

Stepwise Reduction at Magnesium and Beryllium: Cooperative Effects of Carbenes with Redox Non-Innocent α-Diimines

Inorganic Chemistry
2019-08-19 | Journal article | Author
Part of ISSN: 0020-1669
Part of ISSN: 1520-510X
Contributors: Lucas Freeman; Jacob E. Walley; Akachukwu Obi; guocang wang; Diane A. Dickie; Andrew Molino; David J D Wilson; Robert J. Gilliard, Jr.
Source: Self-asserted source
Robert J. Gilliard, Jr.

Metal‐Free Electrochemical Reduction of Carbon Dioxide Mediated by Cyclic(Alkyl)(Amino) Carbenes

2019-04-26 | Journal article
Part of ISSN: 0947-6539
Part of ISSN: 1521-3765
Source: Self-asserted source
Robert J. Gilliard, Jr.
grade
Preferred source (of 2)‎

Isolation of Cyclic(Alkyl)(Amino) Carbene–Bismuthinidene Mediated by a Beryllium(0) Complex

2019-03-21 | Journal article
Part of ISSN: 0947-6539
Part of ISSN: 1521-3765
Source: Self-asserted source
Robert J. Gilliard, Jr.
grade
Preferred source (of 2)‎

Two Carbenes versus One in Magnesium Chemistry: Synthesis of Terminal Dihalide, Dialkyl, and Grignard Reagents

2019-02-11 | Journal article
Part of ISSN: 0276-7333
Part of ISSN: 1520-6041
Source: Self-asserted source
Robert J. Gilliard, Jr.
grade
Preferred source (of 2)‎

Highly Reactive Cyclic(alkyl)(amino) Carbene- and N-Heterocyclic Carbene-Bismuth(III) Complexes: Synthesis, Structure, and Computations

2018-09-17 | Journal article
Part of ISSN: 0020-1669
Part of ISSN: 1520-510X
Source: Self-asserted source
Robert J. Gilliard, Jr.

An isolable magnesium diphosphaethynolate complex

Dalton Transactions
2017 | Journal article
EID:

2-s2.0-85040568268

Contributors: Gilliard, R.J.; Heift, D.; Benko, Z.; Keiser, J.M.; Rheingold, A.L.; Grützmacher, H.; Protasiewicz, J.D.
Source: Self-asserted source
Robert J. Gilliard, Jr. via Scopus - Elsevier

Insertion of sodium phosphaethynolate, Na[OCP], into a zirconium-benzyne complex

Chemical Communications
2017 | Journal article
EID:

2-s2.0-85022086835

Contributors: Kieser, J.M.; Gilliard, R.J.; Rheingold, A.L.; Grützmacher, H.; Protasiewicz, J.D.
Source: Self-asserted source
Robert J. Gilliard, Jr. via Scopus - Elsevier

Synthesis of P<inf>2</inf>C<inf>2</inf>O<inf>2</inf>and P<inf>2</inf>CO: Via NHC-mediated coupling of the phosphaethynolate anion

Chemical Communications
2017 | Journal article
EID:

2-s2.0-85034103985

Contributors: Gilliard, R.J.; Suter, R.; Schrader, E.; Benk, Z.; Rheingold, A.L.; Grützmacher, H.; Protasiewicz, J.D.
Source: Self-asserted source
Robert J. Gilliard, Jr. via Scopus - Elsevier

From the parent phosphinidene-carbene adduct NHCPH to cationic P<inf>4</inf>-rings and P<inf>2</inf>-cycloaddition products

Dalton Transactions
2016 | Journal article
EID:

2-s2.0-84956654192

Contributors: Beil, A.; Gilliard, R.J.; Grützmacher, H.
Source: Self-asserted source
Robert J. Gilliard, Jr. via Scopus - Elsevier
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Peer review (42 reviews for 7 publications/grants)

Review activity for Accounts of chemical research. (1)
Review activity for ACS catalysis. (1)
Review activity for European journal of inorganic chemistry. (2)
Review activity for Inorganic chemistry. (10)
Review activity for Journal of organic chemistry. (1)
Review activity for Journal of the American Chemical Society. (21)
Review activity for Organometallics. (6)