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Rutherford Appleton Laboratory: Didcot, Oxfordshire, GB

(ISIS Facility)
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David Keen

Works (47)

Direct synthesis of an iron metal-organic framework antiferromagnetic glass

2025-01-16 | Preprint
DOI: 10.21203/rs.3.rs-5822781/v1
Contributors: Guillermo Minguez Espallargas; Luis León-Alcaide; Lucía Martínez-Goyeneche; Michele Sessolo; Bruno Vieira; Joao Waerenborgh; José Rodríguez-Velamazán; Oscar Fabelo; Matthew Cliffe; David Keen
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Correction: Local structure and lithium-ion diffusion pathway of cubic Li7La3Zr2O12 studied by total scattering and the Reverse Monte Carlo method

Journal of Materials Chemistry A
2024 | Journal article
DOI: 10.1039/D3TA90219F
Contributors: Haolai Tian; Guanqun Cai; Lei Tan; He Lin; Anthony E. Phillips; Isaac Abrahams; David A. Keen; Dean S. Keeble; Andy Fiedler; Junrong Zhang et al.
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Integrating crystallographic and computational approaches to carbon-capture materials for the mitigation of climate change

Journal of Materials Chemistry A
2024 | Journal article
DOI: 10.1039/D4TA04136D
Contributors: Eric Cockayne; Austin McDannald; Winnie Wong-Ng; Yu-Sheng Chen; Jason Benedict; Felipe Gándara Barragán; Christopher H. Hendon; David A. Keen; Ute Kolb; Lan Li et al.
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Orientational order/disorder and network flexibility in deuterated methylammonium lead iodide perovskite by neutron total scattering

Journal of Materials Chemistry A
2024 | Journal article
DOI: 10.1039/D3TA04586B
Contributors: Jiaxun Liu; Juan Du; Peter B. Wyatt; David A. Keen; Anthony E. Phillips; Martin T. Dove
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Thermally activated structural phase transitions and processes in metal–organic frameworks

Chemical Society Reviews
2024 | Journal article
DOI: 10.1039/D3CS01105D
Contributors: Celia Castillo-Blas; Ashleigh M. Chester; David A. Keen; Thomas D. Bennett
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Author Correction: Resolving length-scale-dependent transient disorder through an ultrafast phase transition

Nature Materials
2024-08 | Journal article
DOI: 10.1038/s41563-024-01974-1
Contributors: Jack Griffiths; Ana F. Suzana; Longlong Wu; Samuel D. Marks; Vincent Esposito; Sébastien Boutet; Paul G. Evans; J. F. Mitchell; Mark P. M. Dean; David A. Keen et al.
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Resolving length-scale-dependent transient disorder through an ultrafast phase transition

Nature Materials
2024-08 | Journal article
DOI: 10.1038/s41563-024-01927-8
Contributors: Jack Griffiths; Ana F. Suzana; Longlong Wu; Samuel D. Marks; Vincent Esposito; Sébastien Boutet; Paul G. Evans; J. F. Mitchell; Mark P. M. Dean; David A. Keen et al.
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Local Structure and Dynamics in MPt(CN)6 Prussian Blue Analogues

Chemistry of Materials
2024-06-11 | Journal article
DOI: 10.1021/acs.chemmater.4c01013
Contributors: Elodie A. Harbourne; Helena Barker; Quentin Guéroult; John Cattermull; Liam A. V. Nagle-Cocco; Nikolaj Roth; John S. O. Evans; David A. Keen; Andrew L. Goodwin
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Formation of a meltable purinate metal–organic framework and its glass analogue

Chemical Communications
2023 | Journal article
DOI: 10.1039/D2CC05314D
Contributors: Alice M. Bumstead; Celia Castillo-Blas; Ignas Pakamorė; Michael F. Thorne; Adam F. Sapnik; Ashleigh M. Chester; Georgina Robertson; Daniel J. M. Irving; Philip A. Chater; David A. Keen et al.
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Local structure and lithium-ion diffusion pathway of cubic Li7La3Zr2O12 studied by total scattering and the Reverse Monte Carlo method

Journal of Materials Chemistry A
2023 | Journal article
DOI: 10.1039/D3TA04495E
Contributors: Haolai Tian; Guanqun Cai; Lei Tan; He Lin; Anthony E. Phillips; Isaac Abrahams; David A. Keen; Dean S. Keeble; Andy Fiedler; Junrong Zhang et al.
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Superstructure and Correlated Na+ Hopping in a Layered Mg-Substituted Sodium Manganate Battery Cathode are Driven by Local Electroneutrality

Chemistry of Materials
2023-12-26 | Journal article
DOI: 10.1021/acs.chemmater.3c02180
Contributors: Euan N. Bassey; Ieuan D. Seymour; Joshua D. Bocarsly; David A. Keen; Guido Pintacuda; Clare P. Grey
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Aufklärung der molekularen Struktur und des Confinements eines in amorphen porösen Polymeren heterogenisierten metallorganischen Katalysators**

Angewandte Chemie
2023-10-26 | Journal article
DOI: 10.1002/ange.202310878
Contributors: Ribal Jabbour; Christopher W. Ashling; Thomas C. Robinson; Arafat Hossain Khan; Dorothea Wisser; Pierrick Berruyer; Ashta C. Ghosh; Alisa Ranscht; David A. Keen; Eike Brunner et al.
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Unravelling the Molecular Structure and Confining Environment of an Organometallic Catalyst Heterogenized within Amorphous Porous Polymers**

Angewandte Chemie International Edition
2023-10-26 | Journal article
DOI: 10.1002/anie.202310878
Contributors: Ribal Jabbour; Christopher W. Ashling; Thomas C. Robinson; Arafat Hossain Khan; Dorothea Wisser; Pierrick Berruyer; Ashta C. Ghosh; Alisa Ranscht; David A. Keen; Eike Brunner et al.
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Survival of Zirconium-Based Metal–Organic Framework Crystallinity at Extreme Pressures

Inorganic Chemistry
2023-07-03 | Journal article
DOI: 10.1021/acs.inorgchem.2c04428
Contributors: Georgina P. Robertson; Sara Mosca; Celia Castillo-Blas; Florencia A. Son; Omar K. Farha; David A. Keen; Simone Anzellini; Thomas D. Bennett
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Meltable, Glass-Forming, Iron Zeolitic Imidazolate Frameworks

Journal of the American Chemical Society
2023-05-24 | Journal article
DOI: 10.1021/jacs.3c01455
Contributors: Luis León-Alcaide; Rasmus S. Christensen; David A. Keen; José L. Jordá; Isaac Brotons-Alcázar; Alicia Forment-Aliaga; Guillermo Mínguez Espallargas
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Which phonons contribute most to negative thermal expansion in ScF3?

APL Materials
2023-04-01 | Journal article
DOI: 10.1063/5.0147610
Contributors: Martin T. Dove; Zhongsheng Wei; Anthony E. Phillips; David A. Keen; Keith Refson
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An N⋯H⋯N low-barrier hydrogen bond preorganizes the catalytic site of aspartate aminotransferase to facilitate the second half-reaction

Chemical Science
2022 | Journal article
DOI: 10.1039/D2SC02285K
Contributors: Victoria N. Drago; Steven Dajnowicz; Jerry M. Parks; Matthew P. Blakeley; David A. Keen; Nicolas Coquelle; Kevin L. Weiss; Oksana Gerlits; Andrey Kovalevsky; Timothy C. Mueser
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Formation of new crystalline qtz-[Zn(mIm)2] polymorph from amorphous ZIF-8

Chemical Communications
2022 | Journal article
DOI: 10.1039/D2CC04241J
Contributors: Michael F. Thorne; Celia Castillo-Blas; Lauren N. McHugh; Alice M. Bumstead; Georgina Robertson; Adam F. Sapnik; Chloe S. Coates; Farheen N. Sayed; Clare P. Grey; David A. Keen et al.
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Mapping short-range order at the nanoscale in metal–organic framework and inorganic glass composites

Nanoscale
2022 | Journal article
DOI: 10.1039/D2NR03791B
Contributors: Joonatan E. M. Laulainen; Duncan N. Johnstone; Ivan Bogachev; Louis Longley; Courtney Calahoo; Lothar Wondraczek; David A. Keen; Thomas D. Bennett; Sean M. Collins; Paul A. Midgley
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Principles of melting in hybrid organic–inorganic perovskite and polymorphic ABX3 structures

Chemical Science
2022 | Journal article
DOI: 10.1039/D1SC07080K
Contributors: Bikash Kumar Shaw; Celia Castillo-Blas; Michael F. Thorne; María Laura Ríos Gómez; Tom Forrest; Maria Diaz Lopez; Philip A. Chater; Lauren N. McHugh; David A. Keen; Thomas D. Bennett
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Modeling the Effect of Defects and Disorder in Amorphous Metal–Organic Frameworks

Chemistry of Materials
2022-10-25 | Journal article
DOI: 10.1021/acs.chemmater.2c01528
Contributors: Irene Bechis; Adam F. Sapnik; Andrew Tarzia; Emma H. Wolpert; Matthew A. Addicoat; David A. Keen; Thomas D. Bennett; Kim E. Jelfs
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Orientational disorder in sulfur hexafluoride: a neutron total scattering and reverse Monte Carlo study

Journal of Physics: Condensed Matter
2022-07-20 | Journal article
DOI: 10.1088/1361-648X/ac6b74
Contributors: Shidong Zhang; Yinze Qin; Sijie Zhang; Min Gao; Matthew G Tucker; David A Keen; Guanqun Cai; Anthony E Phillips; Martin T Dove
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Multivariate analysis of disorder in metal–organic frameworks

Nature Communications
2022-04-21 | Journal article
DOI: 10.1038/s41467-022-29849-6
Contributors: Adam F. Sapnik; Irene Bechis; Alice M. Bumstead; Timothy Johnson; Philip A. Chater; David A. Keen; Kim E. Jelfs; Thomas D. Bennett
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Orientational order and phase transitions in deuterated methane: a neutron total scattering and reverse Monte Carlo study

Journal of Physics: Condensed Matter
2022-01-05 | Journal article
DOI: 10.1088/1361-648X/ac2db8
Contributors: Yinze Qin; Shidong Zhang; Sijie Zhang; Matthew G Tucker; David A Keen; Guanqun Cai; Anthony E Phillips; Martin T Dove
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Glassy behaviour of mechanically amorphised ZIF-62 isomorphs

Chemical Communications
2021 | Journal article
DOI: 10.1039/D1CC03469C
Contributors: Michael F. Thorne; Adam F. Sapnik; Lauren N. McHugh; Alice M. Bumstead; Celia Castillo-Blas; Dean S. Keeble; Maria Diaz Lopez; Phillip A. Chater; David A. Keen; Thomas D. Bennett
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Room temperature crystallography of human acetylcholinesterase bound to a substrate analogue 4K-TMA: Towards a neutron structure

Current Research in Structural Biology
2021 | Journal article
DOI: 10.1016/j.crstbi.2021.08.003
Contributors: Oksana Gerlits; Matthew P. Blakeley; David A. Keen; Zoran Radić; Andrey Kovalevsky
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Stepwise collapse of a giant pore metal–organic framework

Dalton Transactions
2021 | Journal article
DOI: 10.1039/D1DT00881A
Contributors: Adam F. Sapnik; Duncan N. Johnstone; Sean M. Collins; Giorgio Divitini; Alice M. Bumstead; Christopher W. Ashling; Philip A. Chater; Dean S. Keeble; Timothy Johnson; David A. Keen et al.
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Soft-mode anisotropy in the negative thermal expansion material ReO3

Physical Review B
2021-12-02 | Journal article
DOI: 10.1103/PhysRevB.104.214102
Contributors: Tobias A. Bird; Mark G. L. Wilkinson; David A. Keen; Ronald I. Smith; Nicholas C. Bristowe; Martin T. Dove; Anthony E. Phillips; Mark S. Senn
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Illustrated formalisms for total scattering data: a guide for new practitioners. Corrigendum and addendum

Journal of Applied Crystallography
2021-10-01 | Journal article
DOI: 10.1107/S1600576721007664
Contributors: Peter F. Peterson; David A. Keen
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Ionic liquid facilitated melting of the metal-organic framework ZIF-8

Nature Communications
2021-09-29 | Journal article
DOI: 10.1038/s41467-021-25970-0
Contributors: Vahid Nozari; Courtney Calahoo; Joshua M. Tuffnell; David A. Keen; Thomas D. Bennett; Lothar Wondraczek
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Spin-ice physics in cadmium cyanide

Nature Communications
2021-04-15 | Journal article
DOI: 10.1038/s41467-021-22515-3
Contributors: Chloe S. Coates; Mia Baise; Adrian Schmutzler; Arkadiy Simonov; Joshua W. Makepeace; Andrew G. Seel; Ronald I. Smith; Helen Y. Playford; David A. Keen; Renée Siegel et al.
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Mixed hierarchical local structure in a disordered metal–organic framework

Nature Communications
2021-04-06 | Journal article
DOI: 10.1038/s41467-021-22218-9
Contributors: Adam F. Sapnik; Irene Bechis; Sean M. Collins; Duncan N. Johnstone; Giorgio Divitini; Andrew J. Smith; Philip A. Chater; Matthew A. Addicoat; Timothy Johnson; David A. Keen et al.
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Advantages of a curved image plate for rapid laboratory-based x-ray total scattering measurements: Application to pair distribution function analysis

Review of Scientific Instruments
2021-04-01 | Journal article
DOI: 10.1063/5.0040694
Contributors: Daniel J. M. Irving; David A. Keen; Mark E. Light
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Investigating the melting behaviour of polymorphic zeolitic imidazolate frameworks

CrystEngComm
2020 | Journal article
DOI: 10.1039/D0CE00408A
Contributors: Alice M. Bumstead; María Laura Ríos Gómez; Michael F. Thorne; Adam F. Sapnik; Louis Longley; Joshua M. Tuffnell; Dean S. Keeble; David A. Keen; Thomas D. Bennett
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Metal-organic framework and inorganic glass composites

Nature Communications
2020-11-16 | Journal article
DOI: 10.1038/s41467-020-19598-9
Contributors: Louis Longley; Courtney Calahoo; René Limbach; Yang Xia; Joshua M. Tuffnell; Adam F. Sapnik; Michael F. Thorne; Dean S. Keeble; David A. Keen; Lothar Wondraczek et al.
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Quantitative understanding of negative thermal expansion in scandium trifluoride from neutron total scattering measurements

Physical Review B
2020-09-16 | Journal article
DOI: 10.1103/PhysRevB.102.094105
Contributors: Martin T. Dove; Juan Du; Zhongsheng Wei; David A. Keen; Matthew G. Tucker; Anthony E. Phillips
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Total scattering and the pair distribution function in crystallography

Crystallography Reviews
2020-07-02 | Journal article
DOI: 10.1080/0889311X.2020.1797708
Contributors: David A. Keen
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Unusual Breathing Behavior of Optically Excited Barium Titanate Nanocrystals

Crystals
2020-05-01 | Journal article
DOI: 10.3390/cryst10050365
Contributors: Jiecheng Diao; Mathew Cherukara; Ross Harder; Xiaojing Huang; Fucai Zhang; Bo Chen; Andrew Ulvestad; Sanghoon Song; Diling Zhu; David Keen et al.
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Neutron scattering study of the orientational disorder in potassium cyanide

Journal of Physics Communications
2020-02-14 | Journal article
DOI: 10.1088/2399-6528/ab7318
Contributors: Guanqun Cai; Anthony E Phillips; David A Keen; Matthew G Tucker; Martin T Dove
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Structural evolution in a melt-quenched zeolitic imidazolate framework glass during heat-treatment

Chemical Communications
2019 | Journal article
DOI: 10.1039/C8CC09574D
Contributors: Jiayan Zhang; Louis Longley; Hao Liu; Christopher W. Ashling; Philip A. Chater; Kevin A. Beyer; Karena W. Chapman; Haizheng Tao; David A. Keen; Thomas D. Bennett et al.
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Dimensional crossover of correlated anion disorder in oxynitride perovskites

Chemical Communications
2018 | Journal article
DOI: 10.1039/C8CC03462A
Contributors: Hannah Johnston; Ashley P. Black; Paula Kayser; Judith Oró-Solé; David A. Keen; Amparo Fuertes; J. Paul Attfield
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Structural investigations of amorphous metal–organic frameworks formed via different routes

Physical Chemistry Chemical Physics
2018 | Journal article
DOI: 10.1039/C7CP08508G
Contributors: D. A. Keen; T. D. Bennett
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Thermodynamic features and enthalpy relaxation in a metal–organic framework glass

Physical Chemistry Chemical Physics
2018 | Journal article
DOI: 10.1039/C8CP02340A
Contributors: Chao Zhou; Malwina Stepniewska; Louis Longley; Christopher W. Ashling; Philip A. Chater; David A. Keen; Thomas D. Bennett; Yuanzheng Yue
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Neutron and X-ray total scattering study of hydrogen disorder in fully hydrated hydrogrossular, Ca3Al2(O4H4)3

Physics and Chemistry of Minerals
2018-04-13 | Journal article
DOI: 10.1007/s00269-017-0923-0
Contributors: David A. Keen; Dean S. Keeble; Thomas D. Bennett
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Local-scale structures across the morphotropic phase boundary in PbZr1−x Ti x O3

IUCrJ
2018-01-01 | Journal article
DOI: 10.1107/S2052252517016633
Contributors: Nan Zhang; Hiroko Yokota; A. M. Glazer; D. A. Keen; Semën Gorfman; P. A. Thomas; Wei Ren; Zuo-Guang Ye
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Liquid metal–organic frameworks

Nature Materials
2017-11-01 | Journal article
DOI: 10.1038/nmat4998
Contributors: Romain Gaillac; Pluton Pullumbi; Kevin A. Beyer; Karena W. Chapman; David A. Keen; Thomas D. Bennett; François-Xavier Coudert
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Direct visualization of critical hydrogen atoms in a pyridoxal 5′-phosphate enzyme

Nature Communications
2017-10-16 | Journal article
DOI: 10.1038/s41467-017-01060-y
Contributors: Steven Dajnowicz; Ryne C. Johnston; Jerry M. Parks; Matthew P. Blakeley; David A. Keen; Kevin L. Weiss; Oksana Gerlits; Andrey Kovalevsky; Timothy C. Mueser
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Peer review (6 reviews for 5 publications/grants)

Review activity for ACS nano. (1)
Review activity for Angewandte Chemie. (1)
Review activity for Inorganic chemistry. (1)
Review activity for Journal of physical chemistry. (2)
Review activity for Journal of the American Chemical Society. (1)
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