Krishnamoorthy Muralirajan (0000-0003-0742-073X)

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Excited-state palladium-catalysed reductive alkylation of imines: scope and mechanism

Chemical Science

2022 | Journal article | Author

DOI: 10.1039/d2sc02363f

Part of ISSN: 2041-6520

Part of ISSN: 2041-6539

Contributors: Rajesh Kancherla; Krishnamoorthy Muralirajan; Magnus Rueping

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Krishnamoorthy Muralirajan

Paired Electrolysis for Decarboxylative Cyanation: 4-CN-Pyridine, a Versatile Nitrile Source

Organic Letters

2022-09-09 | Journal article | Author

DOI: 10.1021/acs.orglett.2c01897

Part of ISSN: 1523-7060

Part of ISSN: 1523-7052

Contributors: Gadde Sathish Kumar; Prashant S. Shinde; Haifeng Chen; Krishnamoorthy Muralirajan; Rajesh Kancherla; Magnus Rueping

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Krishnamoorthy Muralirajan

Mechanistic insights into photochemical nickel-catalyzed cross-couplings enabled by energy transfer

Nature Communications

2022-05-18 | Journal article

DOI: 10.1038/s41467-022-30278-8

Part of ISSN: 2041-1723

Contributors: Rajesh Kancherla; Krishnamoorthy Muralirajan; Bholanath Maity; Safakath Karuthedath; Gadde Sathish Kumar; Frédéric Laquai; Luigi Cavallo; Magnus Rueping

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Krishnamoorthy Muralirajan

Exploring the Structure and Performance of Cd–Chalcogenide Photocatalysts in Selective Trifluoromethylation

ACS Catalysis

2021-12-17 | Journal article | Author

DOI: 10.1021/acscatal.1c04053

Part of ISSN: 2155-5435

Contributors: Krishnamoorthy Muralirajan; Rajesh Kancherla; Jeremy Bau; Mayur Rahul Taksande; Muhammad Qureshi; Kazuhiro Takanabe; Magnus Rueping

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Krishnamoorthy Muralirajan

Unactivated Alkyl Chloride Reactivity in Excited-State Palladium Catalysis

Organic Letters

2021-09-03 | Journal article | Author

DOI: 10.1021/acs.orglett.1c02467

Part of ISSN: 1523-7060

Part of ISSN: 1523-7052

Contributors: Krishnamoorthy Muralirajan; Rajesh Kancherla; Aidana Gimnkhan; Magnus Rueping

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Krishnamoorthy Muralirajan

1.2.3 Palladium/Photocatalyst Dual Catalysis

Dual Catalysis in Organic Synthesis 1

2020 | Book chapter

DOI: 10.1055/sos-sd-231-00168

Part of ISBN: 9783132429765

Part of ISBN: 9783132429802

Contributors: K. Muralirajan; Magnus Rueping

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Krishnamoorthy Muralirajan

Oxidative Addition to Palladium(0) Made Easy through Photoexcited-State Metal Catalysis: Experiment and Computation

Angewandte Chemie - International Edition

2019 | Journal article

DOI: 10.1002/anie.201811439

EID:

2-s2.0-85059850279

Part of ISBN:

15213773 14337851

Contributors: Kancherla, R.; Muralirajan, K.; Maity, B.; Zhu, C.; Krach, P.E.; Cavallo, L.; Rueping, M.

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Krishnamoorthy Muralirajan via Scopus - Elsevier

Visible Light-Induced Excited-State Transition-Metal Catalysis

Trends in Chemistry

2019 | Journal article

DOI: 10.1016/j.trechm.2019.03.012

EID:

2-s2.0-85066861807

Part of ISBN:

25895974

Contributors: Kancherla, R.; Muralirajan, K.; Sagadevan, A.; Rueping, M.

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Krishnamoorthy Muralirajan via Scopus - Elsevier

Dehydrogenative Aromatization and Sulfonylation of Pyrrolidines: Orthogonal Reactivity in Photoredox Catalysis

Angewandte Chemie - International Edition

2018 | Journal article

DOI: 10.1002/anie.201808427

EID:

2-s2.0-85054839299

Part of ISBN:

15213773 14337851

Contributors: Muralirajan, K.; Kancherla, R.; Rueping, M.

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Krishnamoorthy Muralirajan via Scopus - Elsevier

A simple route to 1,4-addition reactions by Co-catalyzed reductive coupling of organic tosylates and triflates with activated alkenes

Chemical Communications

2017 | Journal article

DOI: 10.1039/c7cc06881f

EID:

2-s2.0-85032866659

Part of ISBN:

1364548X 13597345

Contributors: Hsieh, J.-C.; Chu, Y.-H.; Muralirajan, K.; Cheng, C.-H.

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Krishnamoorthy Muralirajan via Scopus - Elsevier

Cobalt-Catalyzed Mild Ring-Opening Addition of Arenes C−H Bond to 7-Oxabicyclic Alkenes

Advanced Synthesis and Catalysis

2017 | Journal article

DOI: 10.1002/adsc.201601026

EID:

2-s2.0-85011599272

Part of ISBN:

16154169 16154150

Contributors: Muralirajan, K.; Prakash, S.; Cheng, C.-H.

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Krishnamoorthy Muralirajan via Scopus - Elsevier

Cobalt(III)-Catalyzed [5 + 1] Annulation for 2H-Chromenes Synthesis via Vinylic C-H Activation and Intramolecular Nucleophilic Addition

ACS Catalysis

2016 | Journal article

DOI: 10.1021/acscatal.6b00978

EID:

2-s2.0-84973926630

Part of ISBN:

21555435

Contributors: Kuppusamy, R.; Muralirajan, K.; Cheng, C.-H.

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Krishnamoorthy Muralirajan via Scopus - Elsevier

Cobalt-Catalyzed Oxidative Annulation of Nitrogen-Containing Arenes with Alkynes: An Atom-Economical Route to Heterocyclic Quaternary Ammonium Salts

Angewandte Chemie - International Edition

2016 | Journal article

DOI: 10.1002/anie.201509316

EID:

2-s2.0-84955744279

Part of ISBN:

15213773 14337851

Contributors: Prakash, S.; Muralirajan, K.; Cheng, C.-H.

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Krishnamoorthy Muralirajan via Scopus - Elsevier

Easy Access to 1-Amino and 1-Carbon Substituted Isoquinolines via Cobalt-Catalyzed C - H/N - O Bond Activation

Advanced Synthesis and Catalysis

2016 | Journal article

DOI: 10.1002/adsc.201501056

EID:

2-s2.0-84959333014

Part of ISBN:

16154169 16154150

Contributors: Muralirajan, K.; Kuppusamy, R.; Prakash, S.; Cheng, C.-H.

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Krishnamoorthy Muralirajan via Scopus - Elsevier

Rh-Catalyzed Synthesis of Nitrogen-Containing Heterocycles

Transition Metal-Catalyzed Heterocycle Synthesis via C-H Activation

2016 | Book chapter

Part of DOI: 10.1002/9783527691920.ch5

EID:

2-s2.0-85017342076

Contributors: Muralirajan, K.; Cheng, C.-H.

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Krishnamoorthy Muralirajan via Scopus - Elsevier

Rh-catalyzed oxidizing group-directed ortho C-H vinylation of arenes by vinylstannanes

Chemical Communications

2015 | Journal article

DOI: 10.1039/c5cc04211a

EID:

2-s2.0-84939164028

Part of ISBN:

1364548X 13597345

Contributors: Prakash, S.; Muralirajan, K.; Cheng, C.-H.

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Krishnamoorthy Muralirajan via Scopus - Elsevier

Rhodium(III)-catalyzed in situ oxidizing directing group- assisted c-h bond activation and olefination: A route to 2-vinylanilines

Advanced Synthesis and Catalysis

2015 | Journal article

DOI: 10.1002/adsc.201400791

EID:

2-s2.0-85027940441

Part of ISBN:

16154169 16154150

Contributors: Muralirajan, K.; Haridharan, R.; Prakash, S.; Cheng, C.-H.

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Krishnamoorthy Muralirajan via Scopus - Elsevier

Rhodium(III)-catalyzed ortho-arylation of anilides with aryl halides

Advanced Synthesis and Catalysis

2015 | Journal article

DOI: 10.1002/adsc.201400798

EID:

2-s2.0-85027932458

Part of ISBN:

16154169 16154150

Contributors: Haridharan, R.; Muralirajan, K.; Cheng, C.-H.

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Krishnamoorthy Muralirajan via Scopus - Elsevier

Regioselective synthesis of indoles via rhodium-catalyzed C-H activation directed by an in-situ generated redox-neutral group

Advanced Synthesis and Catalysis

2014 | Journal article

DOI: 10.1002/adsc.201400224

EID:

2-s2.0-84900384859

Part of ISBN:

16154169 16154150

Contributors: Muralirajan, K.; Cheng, C.-H.

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Krishnamoorthy Muralirajan via Scopus - Elsevier

Rhodium(III)-catalyzed synthesis of cinnolinium salts from azobenzenes and alkynes: Application to the synthesis of indoles and cinnolines

Chemistry - A European Journal

2013 | Journal article

DOI: 10.1002/chem.201300922

EID:

2-s2.0-84877263135

Part of ISBN:

09476539 15213765

Contributors: Muralirajan, K.; Cheng, C.-H.

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Krishnamoorthy Muralirajan via Scopus - Elsevier

Ru(II)-catalyzed amidation of 2-arylpyridines with isocyanates via C-H activation

Organic Letters

2012 | Journal article

DOI: 10.1021/ol302000a

EID:

2-s2.0-84865263016

Part of ISBN:

15237060 15237052

Contributors: Muralirajan, K.; Parthasarathy, K.; Cheng, C.-H.

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Krishnamoorthy Muralirajan via Scopus - Elsevier

Regioselective synthesis of indenols by rhodium-catalyzed C-H activation and carbocyclization of aryl ketones and alkynes

Angewandte Chemie - International Edition

2011 | Journal article

DOI: 10.1002/anie.201100229

EID:

2-s2.0-79955379597

Part of ISBN:

14337851 15213773

Contributors: Muralirajan, K.; Parthasarathy, K.; Cheng, C.-H.

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Krishnamoorthy Muralirajan via Scopus - Elsevier

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https://orcid.org/0000-0003-0742-073X

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Activities

Works (22)

Excited-state palladium-catalysed reductive alkylation of imines: scope and mechanism

Paired Electrolysis for Decarboxylative Cyanation: 4-CN-Pyridine, a Versatile Nitrile Source

Mechanistic insights into photochemical nickel-catalyzed cross-couplings enabled by energy transfer

Exploring the Structure and Performance of Cd–Chalcogenide Photocatalysts in Selective Trifluoromethylation

Unactivated Alkyl Chloride Reactivity in Excited-State Palladium Catalysis

1.2.3 Palladium/Photocatalyst Dual Catalysis

Oxidative Addition to Palladium(0) Made Easy through Photoexcited-State Metal Catalysis: Experiment and Computation

Visible Light-Induced Excited-State Transition-Metal Catalysis

Dehydrogenative Aromatization and Sulfonylation of Pyrrolidines: Orthogonal Reactivity in Photoredox Catalysis

A simple route to 1,4-addition reactions by Co-catalyzed reductive coupling of organic tosylates and triflates with activated alkenes

Cobalt-Catalyzed Mild Ring-Opening Addition of Arenes C−H Bond to 7-Oxabicyclic Alkenes

Cobalt(III)-Catalyzed [5 + 1] Annulation for 2H-Chromenes Synthesis via Vinylic C-H Activation and Intramolecular Nucleophilic Addition

Cobalt-Catalyzed Oxidative Annulation of Nitrogen-Containing Arenes with Alkynes: An Atom-Economical Route to Heterocyclic Quaternary Ammonium Salts

Easy Access to 1-Amino and 1-Carbon Substituted Isoquinolines via Cobalt-Catalyzed C - H/N - O Bond Activation

Rh-Catalyzed Synthesis of Nitrogen-Containing Heterocycles

Rh-catalyzed oxidizing group-directed ortho C-H vinylation of arenes by vinylstannanes

Rhodium(III)-catalyzed in situ oxidizing directing group- assisted c-h bond activation and olefination: A route to 2-vinylanilines

Rhodium(III)-catalyzed ortho-arylation of anilides with aryl halides

Regioselective synthesis of indoles via rhodium-catalyzed C-H activation directed by an in-situ generated redox-neutral group

Rhodium(III)-catalyzed synthesis of cinnolinium salts from azobenzenes and alkynes: Application to the synthesis of indoles and cinnolines

Ru(II)-catalyzed amidation of 2-arylpyridines with isocyanates via C-H activation

Regioselective synthesis of indenols by rhodium-catalyzed C-H activation and carbocyclization of aryl ketones and alkynes

https://orcid.org/0000-0003-0742-073X

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Activities

Works (22)

Excited-state palladium-catalysed reductive alkylation of imines: scope and mechanism

Paired Electrolysis for Decarboxylative Cyanation: 4-CN-Pyridine, a Versatile Nitrile Source

Mechanistic insights into photochemical nickel-catalyzed cross-couplings enabled by energy transfer

Exploring the Structure and Performance of Cd–Chalcogenide Photocatalysts in Selective Trifluoromethylation

Unactivated Alkyl Chloride Reactivity in Excited-State Palladium Catalysis

1.2.3 Palladium/Photocatalyst Dual Catalysis

Oxidative Addition to Palladium(0) Made Easy through Photoexcited-State Metal Catalysis: Experiment and Computation

Visible Light-Induced Excited-State Transition-Metal Catalysis

Dehydrogenative Aromatization and Sulfonylation of Pyrrolidines: Orthogonal Reactivity in Photoredox Catalysis

A simple route to 1,4-addition reactions by Co-catalyzed reductive coupling of organic tosylates and triflates with activated alkenes

Cobalt-Catalyzed Mild Ring-Opening Addition of Arenes C−H Bond to 7-Oxabicyclic Alkenes

Cobalt(III)-Catalyzed [5 + 1] Annulation for 2H-Chromenes Synthesis via Vinylic C-H Activation and Intramolecular Nucleophilic Addition

Cobalt-Catalyzed Oxidative Annulation of Nitrogen-Containing Arenes with Alkynes: An Atom-Economical Route to Heterocyclic Quaternary Ammonium Salts

Easy Access to 1-Amino and 1-Carbon Substituted Isoquinolines via Cobalt-Catalyzed C - H/N - O Bond Activation

Rh-Catalyzed Synthesis of Nitrogen-Containing Heterocycles

Rh-catalyzed oxidizing group-directed ortho C-H vinylation of arenes by vinylstannanes

Rhodium(III)-catalyzed in situ oxidizing directing group- assisted c-h bond activation and olefination: A route to 2-vinylanilines

Rhodium(III)-catalyzed ortho-arylation of anilides with aryl halides

Regioselective synthesis of indoles via rhodium-catalyzed C-H activation directed by an in-situ generated redox-neutral group

Rhodium(III)-catalyzed synthesis of cinnolinium salts from azobenzenes and alkynes: Application to the synthesis of indoles and cinnolines

Ru(II)-catalyzed amidation of 2-arylpyridines with isocyanates via C-H activation

Regioselective synthesis of indenols by rhodium-catalyzed C-H activation and carbocyclization of aryl ketones and alkynes