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Education and qualifications (3)

University of Virginia: Charlottesville, VA, US

Education
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University of Virginia

University of Virginia: Charlottesville, VA, US

2017-08 to present | Ph.D. (Chemistry)
Education
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Lucas Freeman

College of Charleston: Charleston, SC, US

2013-08 to 2017-05 | B.S. Chemistry (Chemistry and Biochemistry)
Education
Source: Self-asserted source
Lucas Freeman

Works (22)

Isolation and Reactivity of Carbene-Stabilized Carbon Disulfide Radical Anions

Inorganic Chemistry
2025-03-03 | Journal article
DOI: 10.1021/acs.inorgchem.4c05030
Contributors: Michael J. Stopper, Jr.; Akachukwu D. Obi; Haleigh R. Machost; Noah D. McMillion; Andrew Molino; Emma N. Cook; Asa W. Nichols; Lucas A. Freeman; Sara S. Lombardo; Diane A. Dickie et al.
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Crossref

Approaching Dianionic Tetraoxadiborecine Macrocycles: 10‐Membered Bora‐Crown Ethers Incorporating Borafluorenate Units

Angewandte Chemie International Edition
2023-01-26 | Journal article
DOI: 10.1002/anie.202215772
Contributors: Kelsie E. Wentz; Andrew Molino; Lucas A. Freeman; Diane A. Dickie; David J. D. Wilson; Robert J. Gilliard, Jr.
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Crossref

Approaching Dianionic Tetraoxadiborecine Macrocycles: 10‐Membered Bora‐Crown Ethers Incorporating Borafluorenate Units

Angewandte Chemie
2023-01-26 | Journal article
DOI: 10.1002/ange.202215772
Contributors: Kelsie E. Wentz; Andrew Molino; Lucas A. Freeman; Diane A. Dickie; David J. D. Wilson; Robert J. Gilliard, Jr.
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Crossref

Carbene–Calcium Silylamides and Amidoboranes

Organometallics
2022-11-14 | Journal article
DOI: 10.1021/acs.organomet.2c00464
Contributors: Akachukwu D. Obi; Lucas A. Freeman; Samuel J. Coates; Andrew J. H. Alexis; Nathan C. Frey; Diane A. Dickie; Charles Edwin Webster; Robert J. Gilliard, Jr.
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Crossref

Systematic Electronic and Structural Studies of 9-Carbene-9-Borafluorene Monoanions and Transformations into Luminescent Boron Spirocycles

Inorganic Chemistry
2022-10-31 | Journal article
DOI: 10.1021/acs.inorgchem.2c01945
Contributors: Kelsie E. Wentz; Andrew Molino; Lucas A. Freeman; Diane A. Dickie; David J. D. Wilson; Robert J. Gilliard, Jr.
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Crossref

Activation of Carbon Dioxide by 9-Carbene-9-borafluorene Monoanion: Carbon Monoxide Releasing Transformation of Trioxaborinanone to Luminescent Dioxaborinanone

Journal of the American Chemical Society
2022-09-14 | Journal article
DOI: 10.1021/jacs.2c06845
Contributors: Kelsie E. Wentz; Andrew Molino; Lucas A. Freeman; Diane A. Dickie; David J. D. Wilson; Robert J. Gilliard, Jr.
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Crossref

Synthesis and reactivity of low-oxidation-state alkaline earth metal complexes

Nature Synthesis
2022-06-02 | Journal article
DOI: 10.1038/s44160-022-00077-6
Contributors: Lucas A. Freeman; Jacob E. Walley; Robert J. Gilliard, Jr
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Crossref

Soluble, crystalline, and thermally stable alkali CO2− and carbonite (CO22−) clusters supported by cyclic(alkyl)(amino) carbenes

Chemical Science
2021 | Journal article
DOI: 10.1039/D0SC06851A
Contributors: Lucas A. Freeman; Akachukwu D. Obi; Haleigh R. Machost; Andrew Molino; Asa W. Nichols; Diane A. Dickie; David J. D. Wilson; Charles W. Machan; Robert J. Gilliard
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Crossref

Synthetic Investigations of Molecular s-block Organometallic Chemistry Supported by Singlet Carbenes

2021-11-01 | Dissertation or Thesis
DOI: 10.18130/c2q7-3h97
Contributors: Lucas Freeman
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University of Virginia

Reactions of 9-Carbene-9-Borafluorene Monoanion and Selenium: Synthesis of Boryl-Substituted Selenides and Diselenides

Inorganic Chemistry
2021-09-20 | Journal article
DOI: 10.1021/acs.inorgchem.1c02124
Contributors: Kelsie E. Wentz; Andrew Molino; Lucas A. Freeman; Diane A. Dickie; David J. D. Wilson; Robert J. Gilliard, Jr.
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Crossref

N-Heterocyclic Carbene-Mediated Ring Opening of Reduced Diazamagnesacycles

Organometallics
2020-12-28 | Journal article
DOI: 10.1021/acs.organomet.0c00620
Contributors: Akachukwu D. Obi; Lucas A. Freeman; Diane A. Dickie; Robert J. Gilliard, Jr.
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Crossref

Persistent Borafluorene Radicals

Angewandte Chemie International Edition
2020-03-02 | Journal article
DOI: 10.1002/anie.201909627
Contributors: Wenlong Yang; Kelsie E. Krantz; Lucas A. Freeman; Diane A. Dickie; Andrew Molino; Gernot Frenking; Sudip Pan; David J. D. Wilson; Robert J. Gilliard, Jr.
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Crossref

Persistent Borafluorene Radicals

Angewandte Chemie
2020-03-02 | Journal article
DOI: 10.1002/ange.201909627
Contributors: Wenlong Yang; Kelsie E. Krantz; Lucas A. Freeman; Diane A. Dickie; Andrew Molino; Gernot Frenking; Sudip Pan; David J. D. Wilson; Robert J. Gilliard, Jr.
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Crossref

Low-nuclearity magnesium hydride complexes stabilized by N-heterocyclic carbenes

Dalton Transactions
2019 | Journal article
DOI: 10.1039/C9DT03915E
Contributors: Lucas A. Freeman; Jacob E. Walley; Diane A. Dickie; Robert J. Gilliard
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Crossref

Stable Borepinium and Borafluorenium Heterocycles: A Reversible Thermochromic “Switch” Based on Boron–Oxygen Interactions

Chemistry – A European Journal
2019-09-25 | Journal article
DOI: 10.1002/chem.201903348
Part of ISSN: 0947-6539
Part of ISSN: 1521-3765
Source: Self-asserted source
Lucas Freeman

Stepwise Reduction at Magnesium and Beryllium: Cooperative Effects of Carbenes with Redox Non-Innocent α-Diimines

Inorganic Chemistry
2019-08-19 | Journal article
DOI: 10.1021/acs.inorgchem.9b01058
Contributors: Lucas A. Freeman; Jacob E. Walley; Akachukwu D. Obi; Guocang Wang; Diane A. Dickie; Andrew Molino; David J. D. Wilson; Robert J. Gilliard, Jr.
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Crossref

Metal‐Free Electrochemical Reduction of Carbon Dioxide Mediated by Cyclic(Alkyl)(Amino) Carbenes

Chemistry – A European Journal
2019-04-26 | Journal article
DOI: 10.1002/chem.201900316
Contributors: Lauren E. Lieske; Lucas A. Freeman; Guocang Wang; Diane A. Dickie; Robert J. Gilliard, Jr.; Charles W. Machan
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Crossref

Isolation of Cyclic(Alkyl)(Amino) Carbene–Bismuthinidene Mediated by a Beryllium(0) Complex

Chemistry – A European Journal
2019-03-21 | Journal article
DOI: 10.1002/chem.201900458
Part of ISSN: 0947-6539
Part of ISSN: 1521-3765
Source: Self-asserted source
Lucas Freeman

Two Carbenes versus One in Magnesium Chemistry: Synthesis of Terminal Dihalide, Dialkyl, and Grignard Reagents

Organometallics
2019-02-11 | Journal article
DOI: 10.1021/acs.organomet.8b00866
Contributors: Yuen Onn Wong; Lucas A. Freeman; A. Danai Agakidou; Diane A. Dickie; Charles Edwin Webster; Robert J. Gilliard, Jr.
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Crossref

p-Doping Poly(3-hexylthiophene) in Solvent Mixtures

Macromolecular Chemistry and Physics
2018-09-02 | Journal article
DOI: 10.1002/macp.201800146
Part of ISSN: 1022-1352
Contributors: Lucas Freeman; Paul Miller; Marni Sapolsky; David Boucher
Source: Self-asserted source
Lucas Freeman via Crossref Metadata Search

Highly Reactive Cyclic(alkyl)(amino) Carbene- and N-Heterocyclic Carbene-Bismuth(III) Complexes: Synthesis, Structure, and Computations

Inorganic Chemistry
2018-08 | Journal article
DOI: 10.1021/acs.inorgchem.8b01813
Part of ISSN: 0020-1669
Contributors: Guocang Wang; Lucas A. Freeman; Diane A. Dickie; Réka Mokrai; Zoltán Benkő; Robert J. Gilliard
Source: Self-asserted source
Lucas Freeman via Crossref Metadata Search

CCDC 2008073: Experimental Crystal Structure Determination
Source: Self-asserted source
Lucas Freeman
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